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B Boron Compounds: Boron and Noble Gases, Hydrogen
ISBN: 9783662061466 / Angielski / Miękka / 157 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. A broad coverage of boron topics is provided. Structural elucidations and convenient routes to useful hydroboration reagents are presented as well as boron compounds used for medical purposes. Special attention is devoted to theoretical studies and calculations on small boron-hydrogen and boron-noble gas species including molecules like BH, which are rather favorite subjects of theoreticians for testing various methods of calculation.
A broad coverage of boron topics is provided. Structural elucidations and convenient routes to useful hydroboration reagents are presented as well as ...
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Boron and Oxygen
ISBN: 9783662061527 / Angielski / Miękka / 301 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The present issue, Volume 2 of "Boron Compounds" 4th Supplement of the Gmelin Hand book, updates the previous issues by reporting the literature on boron-oxygen systems published up to 1988. For some important recent developments literature is covered through mid-1992; this concerns, for example, the compounds -Ba3 B306h and U B305J which became of interest as materials with nonlinear optical properties. The volume directly com plements the earlier "Boron Compounds" 3rd Supplement Volume 2. In the original literature, alternative formulations are frequently used for the same com pound. This...
The present issue, Volume 2 of "Boron Compounds" 4th Supplement of the Gmelin Hand book, updates the previous issues by reporting the literature on bo...
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Index: Formula Index
ISBN: 9783662061930 / Angielski / Miękka / 281 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The GmeLin FormuLa Index and its First SuppLement covered those voLumes of the Eighth Edition of the GmeLin Handbook which had been issued up to the end of 1979. The present Second SuppLement updates the Index by incLusion of the voLumes which appeared up to the end of 1987. With this Second SuppLement aLL compounds described in the GmeLin Handbook of Inorganic Chemistry in the period between 1924 and 1987 can be Located. The basic structure of the FormuLa Index remains the same as in the previous editions. Computer techniques were empLoyed in the preparation and print of the Second SuppLe...
The GmeLin FormuLa Index and its First SuppLement covered those voLumes of the Eighth Edition of the GmeLin Handbook which had been issued up to the e...
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Gmelin Handbuch Der Anorganischen Chemie: Index
ISBN: 9783662062265 / Angielski / Miękka / 294 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. |
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Sb Organoantimony Compounds Part 4: Compounds of Pentavalent Antimony with Three Sb-C Bonds
ISBN: 9783662063118 / Angielski / Miękka / 250 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. This fourth volume on organoantimony compounds describes pentavalent antimony com pounds of the type R and R . The R denotes an organic group bonded by carbon 3SbX2 3Sb=X to the antimony atom. X represents a group, inorganic or organic, which is bonded to the antimony by an atom other than carbon. The X atoms in R may be part of a 3SbX2 ring system. In the case of bidentate X ligands like 02-, S2-, SO -, CO -, and others, the compounds are placed with the mononuclear RssbX compounds. 2 I once again thank Dr. Margot Becke and Dr. Ekkehard Fluck for the stimulus that led to this book. To the...
This fourth volume on organoantimony compounds describes pentavalent antimony com pounds of the type R and R . The R denotes an organic group bonded b...
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Sb Organoantimony Compounds: Part 5: Compounds of Pentavalent Antimony with Three, Two and One Sb-C Bonds
ISBN: 9783662063149 / Angielski / Miękka / 407 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. This fifth volume on organoantimony compounds continues the description of pentavalent antimony compounds and concludes the entire series. The treatment of pentavalent compounds with three Sb-C bonds began in Part 4 with the RSbX type and is now completed with types RSb(X)Y, RR'SbX , RR'Sb(X)Y, 3 2 3 2 2 2 RR'R"SbX (Section 2.5.1) and the corresponding bi- and trinuclear compounds (Sec- 2 tions 2.5.2, p.87, and 2.5.3, p. 132). R, R', and R" denote different organic groups bonded through carbon to the antimony atom. X and Y represent inorganic or organic groups that are bonded to antimony by...
This fifth volume on organoantimony compounds continues the description of pentavalent antimony compounds and concludes the entire series. The treatme...
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Th Thorium: Compounds with Carbon: Carbonates, Thiocyanates, Alkoxides, Carboxylates
ISBN: 9783662063170 / Angielski / Miękka / 163 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The present volume of the Gmelin thorium series describes the solid thorium-carbon compounds with the exception of the carbides and coordination compounds of the type 4 ThAn. X B, where B is a neutral ligand. The complex equilibria of the Th + ion with C-containing complexing agents are treated in the ThD1 volume. A first look into this volume demonstrates that a very large number of ThlV complexes has 4 been prepared. This may be explained by the fact that the Th + ion is the largest tetravalent ion of the periodic table. Therefore, the preparation of complexes with, e. g., multidentate...
The present volume of the Gmelin thorium series describes the solid thorium-carbon compounds with the exception of the carbides and coordination compo...
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GE Organogermanium Compounds: Part 4: Compounds with Germanium-Hydrogen Bonds
ISBN: 9783662063262 / Angielski / Miękka / 364 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The present volume in the organogermanium series describes mononuclear compounds containing only germanium-carbon and germanium-hydrogen bonds (Chapter 1.3). Germanium hydrides with other additional non-carbon ligands, such as halogen or oxygen bonded groups, appear in later chapters according to the Gmelin principle of the last posi tion. Compounds with Ge-H and Ge-O bonds have already been described in Volume 5, Section 1.5.1.4, pp. 50/62. The present volume covers the literature to the end of 1992 and includes many references up to 1994. The nomenclature recommended by IUPAC has been...
The present volume in the organogermanium series describes mononuclear compounds containing only germanium-carbon and germanium-hydrogen bonds (Chapte...
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Th Thorium: Supplement Volume C 3 Compounds with Nitrogen
ISBN: 9783662063323 / Angielski / Miękka / 125 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. This volume C 3, as a part of the Gmelin "Thorium" Handbook, Series C, describes the thorium-nitrogen compounds. Included are compounds both of technological importance like the nitrides and the nitrates and those of merely scientific interest, such as amides and related compounds. However, due to the decreasing technical importance of the nuclear thorium fuel cycle, especially with the advanced fuels like the nitride ThN, in recent years, the thorium compounds with nitrogen have been investigated much less extensively than the correspond ing uranium compounds. In order to have the data for...
This volume C 3, as a part of the Gmelin "Thorium" Handbook, Series C, describes the thorium-nitrogen compounds. Included are compounds both of techno...
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N Nitrogen: Compounds with Noble Gases and Hydrogen
ISBN: 9783662063354 / Angielski / Miękka / 280 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. "Nitrogen" Suppt. Vol. B 1 describes the compounds of nitrogen with noble gases and, in the major part, binary compounds composed of one nitrogen atom and hydrogen. Nitrogen hydrogen compounds with two and more nitrogen atoms are covered in "Nitrogen" Suppt. Vol. 82. There is some information on various nitrogen-noble gas species, to a large extent because of the interest in their bonding behavior. Experimental data have been obtained chiefly for some singly charged cations, particularly those formed by argon Like ArN + and ArNi. The existence of others has only been established by mass...
"Nitrogen" Suppt. Vol. B 1 describes the compounds of nitrogen with noble gases and, in the major part, binary compounds composed of one nitrogen atom...
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N Nitrogen
ISBN: 9783662063385 / Angielski / Miękka / 188 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. "Nitrogen" SuppL. Vol. 82 continues the description of binary compounds composed of nitrogen and hydrogen (nitrogen hydrides). While" Nitrogen" SuppL. Vol. 81 covers mono- nitrogen compounds, the present volume comprises compounds having two, three, four, or more nitrogen atoms. Hydrazine, N H , and its ions N2Ht and N2H~+ were not included. 2 4 (Reference is made to a voluminous monograph: E.W. Schmidt, Hydrazine and its Deriva- tives: Preparation, Properties, Applications, Chichester 1984, 1088 pages.) Among the dinitrogen compounds, the diazenyl cation, N H+, has been extensively inves- 2...
"Nitrogen" SuppL. Vol. 82 continues the description of binary compounds composed of nitrogen and hydrogen (nitrogen hydrides). While" Nitrogen" SuppL....
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F Fluorine: Compounds with Oxygen and Nitrogen
ISBN: 9783662063415 / Angielski / Miękka / 411 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The present volume, "Fluorine" Suppt. Vol. 4, covers the oxygen compounds of fluorine and the binary fluorine-nitrogen compounds. In the first part "Fluorine and Oxygen," oxygen fluorides OnF m are described in the order of decreasing F: 0 ratio. It finishes with a description of hyperfluorous acid HOF. The second part "Fluorine and Nitrogen" deals with the binary fluorine-nitrogen com pounds. They are subdivided on the basis of the number of nitrogen atoms per molecule. Thus, species such as NFt, NF, NF, and NF are considered first followed by the dinitrogen and 3 2 trinitrogen fluorides NF,...
The present volume, "Fluorine" Suppt. Vol. 4, covers the oxygen compounds of fluorine and the binary fluorine-nitrogen compounds. In the first part "F...
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Th Thorium: Compounds with S, Se, Te and B
ISBN: 9783662063446 / Angielski / Miękka / 149 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The present volume, Thorium C5, deals with the compounds of thorium and sulfur, selenium, tellurium, and boron, as well as with oxoacid compounds of the three chalcogen elements. Thorium borates have already been treated in Thorium C2. In contrast to the corresponding compounds of uranium the thorium sulfides, etc., do not show any nuclear or other technological application; they are only of academic interest, despite some very interest ing electronic properties, especially of the 1: 1 compounds. The thorium-sulfur and the thorium boron systems in particular were studied in detail, so that we...
The present volume, Thorium C5, deals with the compounds of thorium and sulfur, selenium, tellurium, and boron, as well as with oxoacid compounds of t...
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S Sulfur-Nitrogen Compounds: Part 10a: Compounds with Sulfur of Oxidation Number II
ISBN: 9783662063538 / Angielski / Miękka / 324 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida tion number II. The first chapter deals with sulfur imide (S=NH), N-organyl-sulfur imides (S=NR, R = or ganyl), and metal complexes of sulfur imides. N-Organyl-sulfur imides have not been isolated, but they can be trapped, for example, by cycloaddition and stabilized by coordination to transi tion metals. 11 The following chapter present a detailed survey of other 8 -N compounds with one coordinate sulfur, e.g., dithionitrous acid (S=N-SH) and derivatives, the salts of the dithionitryl ion (1 +) (...
The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida tion number II. The first chapter deals with sulfur imide (S=N...
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S Sulfur-Nitrogen Compounds: Compounds with Sulfur of Oxidation Number IV
ISBN: 9783662063651 / Angielski / Miękka / 487 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. PF3, (CH3)3SiCl -> (CH3)3SiF, and RC(O)Cl -> RC(O)F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S)S)2 into R2NCF3, R=alkyl. In organic chemistry, fluorides are easily accessible from alcohols, geminal fluorides RR'CF2 from the respective aldehydes or ketones, and acyl fluorides RC(O)F from carboxylic acides by using DAST. Because DAST is easy to handle and gives clean reactions in syntheses, this Gmelin volume devotes much space to the description of the chemical and physical properties od DAST.
PF3, (CH3)3SiCl -> (CH3)3SiF, and RC(O)Cl -> RC(O)F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S)S)2 into R2NCF3, R=alkyl...
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Rh Rhodium: Coordination Compounds with O- And N-Containing Ligands
ISBN: 9783662064139 / Angielski / Miękka / 275 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. This voLume describes the buLk metaL rhodium and its aLLoys with arsenic to ruthenium in accordance with the GmeLin system. The first section, pages 1 through 37, covers in detaiL the foLlowing properties of the metal: CrystaLlographic properties; seLt-diffusion; me chanicaL properties (tensiLe properties, eLastic moduli, hardness, etc. ); thermaL properties (thermaL expansion, vapour pressure, specific heat, thermaL conductivity, etc. ); eLectricaL and magnetic properties (eLectric resistivity, superconductivity, HaLL effect, thermoeLectric force, magnetic susceptibiLity, etc. );...
This voLume describes the buLk metaL rhodium and its aLLoys with arsenic to ruthenium in accordance with the GmeLin system. The first section, pages 1...
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Cu Organocopper Compounds
ISBN: 9783662064412 / Angielski / Miękka / 251 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The present voLume finaLizes the coverage of mononucLear organocopper compounds with Ligands bonded by one carbon atom. As structuraL eLucidation has not yet received much attention in organocopper chemistry and the aggregation of most products is unknown, the term" mononucLear" has been used as expLained in .. Organocopper Compounds" 1, pp. 3/4. Compounds with aLkyL, aLkenyL, and aryL Ligands have aLready been described in VoL umes 1 (pubLished in 1985) and 2 (pubLished in 1983). The present VoLume 3 contains aLL compounds with aLkynyL, carbonyL, isocyanide, and additionaL Ligands bonded by...
The present voLume finaLizes the coverage of mononucLear organocopper compounds with Ligands bonded by one carbon atom. As structuraL eLucidation has ...
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Sn Organotin Compounds: Dibutyltin-Oxygen Compounds
ISBN: 9783662066140 / Angielski / Miękka / 442 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The present volume continues the series on "Organotin Compounds" which first appeared in 1975 and now comprises a collection of fifteen volumes. The overallplan of the series has been given in the preface of Volume 1. The present Volume 15 continues the description of the mononuclear organotin compounds with tin-oxygen bonds (Chapter 1.4.1 ). Treatment of organotin compounds with tin-sulfur, -selenium, and -tellurium bonds appeared earlier in 9, 1982, and 10, 1983. Chapters 1.4.2 to 1.4.4 of Volumes Volume 15 contains RSn-oxygen compounds with R = butyl, iso-butyl, sec-butyl, and 2...
The present volume continues the series on "Organotin Compounds" which first appeared in 1975 and now comprises a collection of fifteen volumes. The o...
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Sn Organotin Compounds: Part 14: Dimethyltin-, Diethyltin-, and Dipropyltin-Oxygen Compounds
ISBN: 9783662067529 / Angielski / Miękka / 248 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The present voLume continues the series on "Organotin Compounds" which first appeared in 1975 and now comprises a coLLection of fourteen voLumes. The overaLL pLan of the series has been given in the preface of VoLume 1. The present VoLume 14 continues the description of the mononucLear organotin compounds with tin-oxygen bonds (Chapter 1.4.1). Treatment of organotin compounds with tin-sulfur, -selenium, and -teLLurium bonds appeared earLier in Chapters 1.4.2 to 1.4.4 of VoLumes 9, 1982, and 10, 1983. VoLume 14 contains RSn-oxygen compounds with R = methyL, ethyL, and prapyL, covering 2 the...
The present voLume continues the series on "Organotin Compounds" which first appeared in 1975 and now comprises a coLLection of fourteen voLumes. The ...
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Fe Organoiron Compounds: Mononuclear Compounds 11
ISBN: 9783662069172 / Angielski / Miękka / 448 str. Termin realizacji zamówienia: ok. 5-8 dni roboczych. The present volume is a continuation of Series B on the mononuclear organoiron compounds. It covers the literature completely to the end of 1979 and includes occa sional references to the literature up to 1982. This volume begins the description of compounds with 5L ligands, i.e., ligands bonded to the iron atom by five carbon atoms. 5LFe compounds are numerous, particu larly those where 5L is cyclopentadienyl. The stability of a 5LFe unit permits many different ligands at the other three coordination sites of the iron atom. Thus the present volume can only cover apart of the 5L compounds....
The present volume is a continuation of Series B on the mononuclear organoiron compounds. It covers the literature completely to the end of 1979 and i...
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