Rh Rhodium: Coordination Compounds with O- And N-Containing Ligands

ISBN-13: 9783662064139 / Angielski / Miękka / 2013 / 275 str.

G. R. Watts; Kurt Swars

Opis

This voLume describes the buLk metaL rhodium and its aLLoys with arsenic to ruthenium in accordance with the GmeLin system. The first section, pages 1 through 37, covers in detaiL the foLlowing properties of the metal: CrystaLlographic properties; seLt-diffusion; me chanicaL properties (tensiLe properties, eLastic moduli, hardness, etc. ); thermaL properties (thermaL expansion, vapour pressure, specific heat, thermaL conductivity, etc. ); eLectricaL and magnetic properties (eLectric resistivity, superconductivity, HaLL effect, thermoeLectric force, magnetic susceptibiLity, etc. ); eLectrochemicaL behaviour and chemicaL reactions. A number of subject matters on metaLlic rhodium are aLready contained together with those of other pLatinum group metals in appropriate chapters of "PLatinum" SuppL. VoL. A 1, 1986. These incLude 1) preparation and eLectrodeposition, 2) zone-refining operations, and 3) chemicaL vapour deposition, sputtering, and thermaL evaporation. Likewise, "PLatinum" SuppL. VoL. 2, 1989, aL ready contains information on the 1) separa tion and properties of the Rh isotopes, 2) physicaL properties of the Rh atom and the atomic 2 ions Rh] and Rh +, 3) the formation of Rh cLusters, and 4) the moLecuLar properties of Rh . 2 The second and major portion of this voLume, pp. 38 to 273, deaLs with the physicaL and chemicaL properties of rhodium aLloys. Phase diagrams of a Large number of binary and muLticomponent systems are treated in detaiL as weLL as the crystaLlographic and other properties of many intermetalLic compounds.

Spis treści

The Metal.- 1 Crystallographic Properties.- 2 Self-Diffusion.- 3 Mechanical Properties.- 4 Thermal Properties.- 5 Electrical and Magnetic Properties.- 6 Electrochemical Behaviour.- 7 Chemical Reactions.- Alloys of Rhodium.- 1 Alloys with Arsenic.- 2 Alloys with Antimony.- 3 Alloys with Bismuth.- 4 Alloys with Alkali Metals.- 5 Alloys with Alkaline Earth Metals.- 6 Alloys with Zinc, Cadmium and Mercury.- 7 Alloys with Aluminium.- 8 Alloys with Gallium and Indium.- 9 Alloys with Scandium and Yttrium.- 10 Alloys with Lanthanum.- 11 Alloys with Cerium.- 12 Alloys with Praseodymium, Neodymium, Samarium and Europium.- 13 Alloys with Gadolinium.- 14 Alloys with Terbium.- 15 Alloys with Dysprosium and Holmium.- 16 Alloys with Erbium.- 17 Alloys with Thulium, Ytterbium, and Lutetium.- 18 Alloys with Titanium.- 19 Alloys with Zirconium.- 20 Alloys with Hafnium.- 21 Alloys with Thorium.- 22 Alloys with Germanium.- 23 Alloys with Tin.- 24 Alloys with Lead.- 25 Alloys with Vanadium.- 26 Alloys with Niobium.- 27 Alloys with Tantalum.- 28 Alloys with Chromium.- 29 Alloys with Molybdenum.- 30 Alloys with Tungsten.- 31 Alloys with Uranium.- 32 Alloys with Manganese.- 33 Alloys with Nickel.- 34 Alloys with Cobalt.- 35 Alloys with Iron.- 36 Alloys with Copper.- 37 Alloys with Silver.- 38 Alloys with Gold.- 39 Alloys with Ruthenium.- Physical Constants and Conversion Factors.