Two-Dimensional NMR Methods for Establishing Molecular Connectivity: A Chemist's Guide to Experiment Selection, Performance, and Interpretation

ISBN-13: 9780471187073 / Angielski / Twarda / 1988 / 528 str.

G. E. Martin; Andrew S. Zektzer; A. S. Zektzer

Opis

This guide to two-dimensional NMR spectroscopy helps the novice who want e the technique, but needs a path through the bewildering array of metho acronyms and the mathematical rigor found in most books.
The authors provide a clear explanation of experiment performance, param lection, data processing and presentation as well as a description of wh rmation is provided by each experiment and how it is extracted and inter They group presentations of two-dimensional NMR experiments according t zation, e.g. COSY, LRCOSY, ZQCOSY, DQCOSY ... for establishing proton-pr nnectivities.
The book also presents spectra of the same model compound using various ues to enable the reader to make direct comparisons and facilitate his e nt selection. Examples of the concerted utilization of various two-dimen NMR experiments to solve complex structural problems are also given.

Spis treści

Introduction and Practical Considerations of Two–Dimensional NMR Spectroscopy.

Heteronuclear Chemical shift Correlation.

Relayed Coherence Transfer and Related 2D–NMR Experiments.

13—C–13—C Double Coherence 2D–NMR. The Inadequate Experiments.

Applications Problems.

Solutions to Problems.

Index.