Nanostructured Lead, Cadmium, and Silver Sulfides: Structure, Nonstoichiometry and Properties

ISBN-13: 9783319563862 / Angielski / Twarda / 2017 / 317 str.

Stanislav I. Sadovnikov; Andrey A. Rempel; Aleksandr I. Gusev

Opis

This book presents and analyzes the influence of small size particles of lead, cadmium and silver sulfide on the properties of nonstoichiometric semiconductors. The effect of nanoparticle size and nonstoichiometry on the band gap, optical and thermal properties of nanostructured sulfides is also considered.

Spis treści

LIST OF MAIN NOTATIONS                                                                                   

PREFACE                                                                                                                           

References                                                                                                                     

1    SIZE CHARACTERIZATION OF NANOSTRUCTURED

      MATERIALS                                                                                                               

1.1 Concept of Nanostructured Material                                                                

1.2 Methods of Evaluation of the Size of Small Particles                                                  

1.2.1 Electron Microscopy                                                                                   

1.2.2 X-Ray Diffraction Method                                                                        

1.2.3 Sedimentation, Photon Correlation Spectroscopy,

Gas Adsoption, and Gas Filtration                                                                      

References                                                                                                                    

2    NANOSTRUCTURED LEAD SULFIDE PbS                                                     

2.1 Methods for the Preparation of Nanostructured Lead Sulfide:

      From Colloidal Solutions to Thin Films                                                                   

2.1.1 Colloidal Solutions of Lead Sulfide Nanoparticles                                

2.1.2 Analysis of the Formation Conditions of Lead Sulfide in

Aqueous Solutions                                                                                                 

2.1.3 Deposition of Lead Sulfide Nanopowders                                              

2.1.4 Deposition of Lead Sulfide Particles with Different Morphology      

2.1.5 Lead Sulfide Quantum Dots                                                                      

2.1.6 Nanostructured Lead Sulfide Films                                                          

2.2 Crystal Structures of Nanoparticles, Nanopowders, and Nanofilms of

Lead Sulfide                                                                                                                 

2.2.1 Crystal Structure of Nanopowders and Quantum Dots                        

2.2.2 Crystal Structures of Nanofilms                                                                

2.2.3 Correlations of Sulfur Atoms S in PbS Nanostructured Films             

2.3 Properties of Nanostructured Lead Sulfide                                                     

2.3.1 Optical Properties and Band Gap                                                             

2.3.2 Thermal Properties                                                                                   

2.3.3 Stability of Nanostructured Lead Sulfide                                            

2.4 Application of Nanostructured Lead Sulfide                                              

References                                                                                                                

<3 NANOSTRUCTURED CADMIUM SULFIDE CdS                                          

3.1 Chemical Deposition of Nanostructured Cadmium Sulfide CdS            

3.1.1 Formation of Aqueous Colloidal Solutions of CdS                          

3.1.2 Formation of CdS Nanoparticles                                                         

3.1.3 Deposition of CdS Film on Substrates                                                 

3.2 Synthesis of CdS Nanoparticles in Glass Matrix                                       

3.3 Features of Crystal Structure of CdS Nanoparticles                                 

3.3.1 Non-periodicity in Sulfide Nanoparticles with Close-pace

Structures                                                                                                            

3.3.2 Visualization of “Average” Long-range Order in the

Non-periodic Structure of CdS Nanoparticle                                              

3.4 Optical Properties of Nanostructured CdS                                                 

References                                                                                                               

4 NANOSTRUCTURED SILVER SULFIDE Ag2S                             

4.1 Methods of Synthesis of Nanostructured Silver Sulfide Ag₂S                

4.1.1 Synthesis by Decomposition of Molecular Precursors                     

4.1.2 Synthesis of Nanostructures Silver Sulfide with Different

Morphology                                                                                                        

4.1.3 Biotechnological and Other Methods for Preparing

Nanostructured Ag₂S Silver Sulfide                                                               

4.2 Crystal Structure of Coarse-Crystalline and Nanostructured

Ag₂S Silver Sulfide                                                                                                  

4.2.1 Crystal Structure of Artificial Coarse-Crystalline a-Ag₂S

Silver Sulfide                                                                                                      

4.2.2 Crystal Structure and Nonstoichiometry of Nanostructured

a-Ag₂S Silver Sulfide                                                                                         

4.2.3 In Situ High-Temperature Study of “Acanthite a-Ag₂S –

Argentite 2S” Phase Transformation                                                    

4.2.4 Thermal Expansion of Acanthite a-Ag_{2S and Argentite b-Ag2S}    

4.3 Universal Approach to Synthesis of Silver Sulfide in the Form

of Nanopowders, Quantum Dots, Core-Shell Nanoparticles,

and Heteronanostructures                                                                                    

4.3.1 Green Synthesis of Nanostructured Ag₂S Without Hazardous

Substances                                                                                                          

4.3.2 Coarse-crystalline Ag₂S powders                                                          

4.3.3 Deposited Ag₂S Nanopowders                                                              

4.3.4 Colloidal Solutions of Ag₂S Quantum Dots                                      

4.3.5 Core-Shell Ag₂S@C Nanoparticles                                                       

4.3.6 Ag₂S/Ag heteronanostructures                                                              

4.4 Hydrochemical Bath Deposition: Advantages and Challenges               

Appendix                                                                                                                 

References                                                                                                              

NAME INDEX                                                                                                            

SUBJECT INDEX                                                                                                      

 

O autorze

Dr. Stanislav I. Sadovnikov is currently a senior research scientist in the Laboratory of nonstoichiometric compounds of the Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences. He has studied the synthesis, structure and properties of nanostructured semiconducting sulfides for more than 10 years and is a recognized expert in the field of nanosized sulfide synthesis. He is an author of two review articles and more than 60 scientific articles.

Prof. Dr. Aleksandr I. Gusev is chief research scientist of the Laboratory of nonstoichiometric compounds in the Institute of Solid State Chemistry of the Russian Academy of Sciences. He has been exploring crystal and electronic structure and properties of novel nonstoichiometric compounds including carbides, sulfides, and oxides, and nanostructured advanced materials for more than 40 years. He is the author of 16 monographs including “Disorder and Order in Strongly Nonstoichiometric Compounds”, Springer (2001), “Nanocrystalline Materials”, Cambridge (2004), “Tungsten Carbides: Structure, Properties and Application in Hardmetals”, Springer (2013), 23 reviews articles and more than 250 scientific articles.

Prof. Dr. Andrey A. Rempel is a head of the Laboratory of nonstoichiometric compounds of the Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences. His current research interests are solid state physics, theory of phase transformations, atomic ordering in strongly nonstoichiometric compounds, nonstoichiometry and atomic defects in nanocrystalline substances including carbides, oxides, and sulfides. He is author of 10 monographs in English and Russian, 11 review articles and more than 200 scientific publications.  

 

Blurb

This book presents and analyzes the influence of small size particles of lead, cadmium and silver sulfide on the properties of nonstoichiometric semiconductors. Important nonstoichiometry aspects in nanostructures are discussed, such as the distribution of sulfur atoms in nanofilms, a non-periodic distribution of the atomic planes in nanoparticles, interdependent changes in crystal structure of nanocrystalline material. Tuning the stoichiometry allows to obtain superionic conductivity and catalytic activity under visible light. The wavelength of the luminescence of nanoparticles changes with the size of the nanoparticles. Various methods to prepare nanostructured sulfides are described. Special attention is given to the hydrochemical bath deposition as a universal method for the synthesis of sulfides as nanofilms, stable colloidal solutions, quantum dots, isolated nanoparticles with a protective shell and heteronanostructures. The effect of nanoparticle size and nonstoichiometry on the band gap, optical and thermal properties of nanostructured sulfides is also considered. The novel applications of sulfide nanoparticles in nanoelectronics, catalysis, nanobiology and nanomedicine are sketched.