NMR and Chemistry: An introduction to modern NMR spectroscopy, Fourth Edition

ISBN-13: 9780748743445 / Angielski / Miękka / 2000 / 400 str.

B. E. Mann

Opis

This is an introduction to current high resolution NMR practice. It provides the physical background to NMR spectroscopy from the point of view of the whole periodic table rather than concentrating on the narrow applications of 1H and 13C NMR spectroscopy. Examples and many new problems, mainly from the recent inorganic /organometallic chemistry literature support the text throughout. Mathematics is kept to a minimum.

Spis treści

THE THEORY OF NUCLEAR MAGNETIZATIONThe Properties of the Nucleus of an AtomThe Nucleus in a Magnetic FieldThe Source of the NMR SignalA Basic NMR SpetrometerQuestionsTHE MAGNETIC FIELD AT THE NUCLEUS: NUCLEAR SCREENING THE CHEMICAL SHIFTEffects Due to the MoleculeIsotope EffectsEffects Due to Unpaired ElectronsThe Chemical ShiftNote on Sample Preparation, Standardization, and Solvent and Temperature EffectsQuestionsINTERNUCLEAR SPIN-SPIN COUPLINGThe Mutual Effects of Nuclear Magnets on Resonance PositionsThe Appearance of Multiplets Arising form Spin-Spin CouplingSpin-Spin Coupling SatellitesThe Description of Spin SystemsSecond-Order EffectsQuestionsNUCLEAR MAGNETIC RELAXATIONRelaxation Processes in Assemblies of Nuclear SpinsDipole-Dipole RelaxationQuardrupolar RelaxationSpin Rotation Relaxation: Detailed Molecular MotionChemical Shift Anisotropy RelaxationScalar RelaxationExamples of 13C Relaxation TimesQuestionsTHE SPECTROMETERThe Magnet and Field HomogeneityThe ProbeField-Frequency LockThe TransmitterThe Detection SystemProduction of the SpectrumRapid Multiple PulsingManipulations of Collected DataQuestionsMAKING THE SPINS DANCEDecouplingComposite PulsesRefocusing PulseQuestionsNMR SPECTRA OF EXCHANGING AND REACTING SYSTEMSSystems at EquilibriumReaction Monitoring of Systems not at EquilibriumQuestionsMULTIPLE RESONANCE AND ONE-DIMENSIONAL PULSE SEQUENCESDecoupling Difference SpectroscopyThe Nuclear Overhauser EffectOne-Dimensional Mutliphase SequencesExercises in Spectral InterpretationTWO-DIMENSIONAL NMR SPECTROSCOPYJ-Resolved Two-Dimensional NMR SpectroscopyHomonuclear COSY NMR SpectroscopyHeteronuclear COSY NMR SpectroscopyHOHAHA or TOCSYTwo-Dimensional INADEQUATEOverhauser and Magnetization Transfer Based Two-Dimensional NMR SpectroscopyInverse DetectionThree-Dimensional NMR SpectroscopyQuestionsMAGNETIC RESONANCE IMAGING AND BIOMEDICAL NMRProducing an ImageWhole Body ImagingDiffusion and FlowChemical Shift ImagingBiological Uses of Imaging - Imaging MicroscopyIndustrial Uses of Imaging TechniquesBiomedical NMRHIGH-RESOLUTION SOLID-STATE NMRMagic Angle SpinningSpin-1/2 Nuclei with Low Magnetogyric RatiosI=1/2 Nuclei with High Magnetogyric RatiosMAS of Quadropolar NucleiSome ApplicationsDeuterium, An Integral-Spin NucleusQuestionsBibliographyAnswers to QuestionsIndex

O autorze

Akitt, J.W.; Mann, B. E.