C-H Activation

ISBN-13: 9783642263590 / Angielski / Miękka / 2012 / 380 str.

Jin-Quan Yu;Zhangjie Shi

Opis

Table of Contents - Synthesis in the Key of Catellani: Norbornene-Mediated ortho C-H Functionalization - Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation - Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C-H and C-Hal Bonds - Pd-Catalyzed C-H Bond Functionalization on the Indole and Pyrrole Nucleus - Remote C-H Activation via Through-Space Palladium and Rhodium Migrations - Palladium-Catalyzed Aryl-Aryl Bond Formation Through Double C-H Activation - Palladium-Catalyzed Allylic C-H Bond Functionalization of Olefins - Ruthenium-Catalyzed Direct Arylations Through C-H Bond Cleavages - Rhodium-Catalyzed C-H Bond Arylationof Arenes - Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C-H Bonds - Functionalization of Carbon-Hydrogen Bonds Through Transition Metal Carbenoid Insertion - Metal-Catalyzed Oxidations of C-H to C-N Bonds

Recenzje

From the reviews:

"C-H Activation is a collection of 12 independent chapters, written by renowned authors. ... The descriptions of future perspectives, applications ... experimental procedures at the end of the chapters will be very valuable to readers, particularly students. ... I strongly recommend the book ... intellectually rewarding, and promising avenues of research within organic and organometallic chemistry. It is an essential reference source for the practitioners in the field for many years to come, and it should have a privileged spot on many bookshelves." (Rubén Martín Romo, Angewandte Chemie, Vol. 50, 2011)

Spis treści

Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization.- Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation.- Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds.- Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus.- Remote C–H Activation via Through-Space Palladium and Rhodium Migrations.- Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation.- Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins.- Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages.- Rhodium-Catalyzed C–H Bond Arylation of Arenes.- Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds.- Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion.- Metal-Catalyzed Oxidations of C–H to C–N Bonds.