Uniqueness of 2-Oxo-Electrophiles Reactions with Typical Nucleophiles

ISBN-13: 9786139921591 / Angielski / Miękka / 2018 / 68 str.

Satyanarayana Battula

Opis

Aldehyde and its various electrophilic forms reactions and their pathways are changed steadily by an involvement of electron withdrawing 2-Oxo group. This 2-Oxo group in 2-Oxoaldehyde (2OA) makes distinctive than compare to the regular aldehyde as 2OA and its other variants enhance their electrophilicities to a peculiar level and that levels may adequate to overcome a new energy barrier for a newer reaction. In addition, this enhanced electrophilicity may cause to requirement of different reaction conditions, for example these reactions generally do not need the assistance of either acid or base catalyst that's quite common in aldehyde reactions. Consequently, these reactions may require different reaction parameters and thereby, produce newer reactions in terms of synthesis of either exigent chemical bonds (C-C, C-N, C-O, C-S and etc.) or biologically valuable functionalized heterocycles from cheaper materials in economical approaches. This 2-Oxo chemistry certainly offers a solution to the regular need to the synthetic chemistry.

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O autorze

Battula, Satyanarayana
Dr. Satyanarayana Battula obtained his PhD from Indian Institute of Integrative Medicine (CSIR, India) wherein his findings are focused completely on fundamental 2-Oxo based electrophiles and their reactions with selective nucleophiles. Then he moved to Uka Tarsadia University, Gujarat as an Asst. Professor and has been working since 2016.