The development of polymers as an important class of material was inhibited at the first by the premature failure of these versatile compounds in many applications. The deterioration of important properties of both natural and synthetic polymers is the result of irreversible changes in composition and structure of polymers molecules. As a result of these reactions, mechanical, electrical and/or aesthetic properties are degraded beyond acceptable limits. It is now generally recognized that stabilization against degradation is necessary if the useful life of polymers is to be extended...
The development of polymers as an important class of material was inhibited at the first by the premature failure of these versatile compounds in many...
The discoveries of organometallic catalysts for olefin polymerization by Karl Ziegler and that of stereoregular olefin polymers by Giulio Natta are probably the two most important achievements in the areas of catalysis and polymer chemistry in the second half of this century. They led to the development of a new branch of chemical industry, and to a large volume production of high-density and linear low-density polyethylene, isotactic polypropylene, ethylene-propylene rubbers, isotactic poly I-butene, and poly-4-methyl-l-pentene. These discoveries merited the Nobel prize, which was awarded to...
The discoveries of organometallic catalysts for olefin polymerization by Karl Ziegler and that of stereoregular olefin polymers by Giulio Natta are pr...
Thirty years ago, Zavoisky, in Moscow (USSR), reported the first successful experi mental observations of the ESR phenomenon. Its application to polymer problems began about 20 years ago. ESR belongs to the most specific and useful methods in the study of polymer reactions. The main purpose of this book is to collect the present available information on the applications of electron spin resonance (ESR) spectroscopy in polymer research. The book has been written both for those who want an introduction to this field, and for those who are aheady familiar with ESR and are interested in...
Thirty years ago, Zavoisky, in Moscow (USSR), reported the first successful experi mental observations of the ESR phenomenon. Its application to polym...
Many excellent volumes have been written on the chemistry of cellulose and its derivatives. Judging by the number of conferences which have been assembled to deal with the topic, cellulose and its derivatives continue to arouse great scientific interest. Matching this interest has been the development in copolymer science and technology. In both instances the driving force has been the search for products having useful, new or interesting properties. It appeared inevitable that these two concepts would be brought together at some time in the research and development of cellulosic copolymers....
Many excellent volumes have been written on the chemistry of cellulose and its derivatives. Judging by the number of conferences which have been assem...
The present monograph is intended as an introduction into a field which certainly did not receive proper attention in the past. It is one of the aims of this book to verify this suppo sition. The author hopes to show that the technique of the measurement of flow birefringence can fulfil an important com plementary task in polymer melt rheology. From this point it is expected that the present monograph will attract the atten tion of polymer scientists in general, and of rheologists and process engineers in particular. Certainly, the fourth chapter will appeal to the latter group. As a teacher...
The present monograph is intended as an introduction into a field which certainly did not receive proper attention in the past. It is one of the aims ...
This book has grown out of several courses oflectures held at the University of Mainz in the years 1978 to 1981, at the Ecole Poly technique Federal, Lausanne, and at the University of Fribourg, Switzerland. The last two courses were held in the framework of the "3e Cycle" lectures in June 1981. According to this genesis, the emphasis of the book lies on a unified and concise approach to introducing polymer spectroscopy rather than on completeness which, by the way, could hardly be achieved in a single volume. In contrast to other books on this subject, equal weight is given to electronic...
This book has grown out of several courses oflectures held at the University of Mainz in the years 1978 to 1981, at the Ecole Poly technique Federal, ...
The development of polymers as an important class of material was inhibited at the first by the premature failure of these versatile compounds in many applications. The deterioration of important properties of both natural and synthetic polymers is the result of irreversible changes in composition and structure of polymers molecules. As a result of these reactions, mechanical, electrical and/or aesthetic properties are degraded beyond acceptable limits. It is now generally recognized that stabilization against degradation is necessary if the useful life of polymers is to be extended...
The development of polymers as an important class of material was inhibited at the first by the premature failure of these versatile compounds in many...
The first edition of this book had been written with the special aim to provide the necessary information for an understanding of the deformation and scission of chain molecules and its role in polymer fracture. In this field there had been an intense ac tivity in the sixties and early seventies. The new results from spectroscopical (ESR, IR) and fracture mechanics methods reported in the first edition had complemented in a very successful way the conventional interpretations of fracture behavior. The extremely friendly reception of this book by the polymer community has shown that the...
The first edition of this book had been written with the special aim to provide the necessary information for an understanding of the deformation and ...
Polymer composites represent a field of intense and growing interest to consumers and producers of plastics. They are used to solve the most acute problems: energy and oil conservation, improvement of the properties of polymer materials, and the increase of their use. Even special problems, such as inflammability of plastics and industrial wastes, are closely connected with polymer composites. The achievements in this field are well known. Polymer composites have been widely used in building, furniture, electric appliances, cars, and other fields. Their production is growing at a higher rate...
Polymer composites represent a field of intense and growing interest to consumers and producers of plastics. They are used to solve the most acute pro...