Ion Exchange Membranes: Design, Preparation, and Applications

ISBN-13: 9783527351947 / Angielski / Twarda / 2024 / 450 str.

Yaoming (University of Science and Technology of China (USTC

Spis treści

1. INTRODUCTION2. FUNDAMENTALS AND CHARACTERIZATIONS2.1. Donnan Equilibrium2.2. Mass Transport2.3. Limiting current density2.4. Concentration polarization2.5. Water transport2.6. Membrane scaling and fouling2.7. Physico-chemical characterizations2.8. Electro-chemical characterizations2.9 Permselectivity2.10 Conductivity2.11 Alkali resistances2.12 Desalination performance2.13 Single-cell performance3. SIDE-CHAIN ARCHITECTURE MANIPULATION FOR IEMS PREPARATION3.1 Types of side-chain topology3.2 Construction of self-assembly hyperbranched networks3.3 Construction of ion-conducting channels3.4 Construction of dynamic transfer regions3.5 Construction of cation-dipole interactions4. POLYACYLATION FOR IEMS PREPARATION4.1. Principle of polyacylation4.2. Polyacylatio of perylene-based aliphatic polyimides4.3. Polyacylation of SPEKs-based IEMs4.4. Polyacylation of Crown-based IEMs4.5 Others5. SUPERACID-CATALYST POLYMERIZATION FOR IEMS PREPARATION5.1. Basic of superacid5.2 Principle of superacid-catalyst5.3. Superacid-catalyst polymers5.4. Superacid-catalyst polymerization for IEMs preparation5.5 Others6. INTRINSIC MICROPOROSITY FOR IEMS PREPARATION6.1 Ion transports behavior in space-confined membrane6.2 Principle of intrinsic microporosity polymer6.3 PIM-1 based IEMs6.4 Tröger?s Based IEMs6.5 Other intrinsic microporisity IEMs7. IN-SITU POLYMERIZATION FOR IEMS PREPARATION7.1. Conventional methods for IEMs preparation7.2. Semi-interpenetrating polymer network7.3. Pore-filling7.4. Solvent-free Strategy7.5 In-situ polymerization8. SPECIAL IEMS PREPARATION8.1 Monovalent selective IEMs8.2 Proton blocking anion exchange membrane8.3 Dense-structure IEMs8.4 High-temperature tolerance IEMs8.5 Others9. APPLICATIONS9.1. Diffusion Dialysis9.2. Electrodialysis9.3. Bipolar membrane electrodialysis9.4. Selective electrodialysis9.5 Metathesis electrodialysis9.6 Ion-distillation9.7. Reverse electrodialysis9.8. Full Cell9.9. Aqueous flow battery9.10. Others

O autorze

Dr. Tongwen Xu is a full-time Professor of Chemistry Engineering at University of Science and Technology of China (USTC). He obtained B.E (1989) and M.E. degree (1992) from Hefei University and Technology and Ph. D from Tianjin University (1995). Dr. Xu joined the USTC as an associate professor in 1997 was promoted to professor in 2001. Dr. Xu was a short-term visiting scientist of the University of Tokyo (2000), Tokyo Institute of Technology (2001) and also a Brain-Pool Professor of Korea in Gwangju Institute of Science and Technology (2006-2007). The research interests of Dr. Xu are focused on the development and practical applications of ion exchange membranes. Prof. Xu has authored more than 500 publications, 6 Books, 20 Chapters, and holds more than 80 issued China Patents for ion exchange membranes and related processes. He is named as a highly cited researcher by Thomson Reuters (ISI Web of Knowledge) with over 20000+ citations and H-index of 74.