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Over the past four decades
tris(diimine)Ru(II) complexes, particularly [Ru(bpy)3]2+,
have attracted much attention as they can be used as
potential solar energy converters and as effective
sensitizers in the photolysis of water and the influence of
diimine ligands have been examined. As many biological
electron-transfer systems are based on copper and iron
coordinated mainly to sulfur donor sites, we have
investigated the effect of incorporating these donors on
spectral and...