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This primer addresses the chemistry of the second and third row d-block metals and assumes a knowledge of the chemistry of the first row metals. Beginning with a summary of basic properties, the book covers periodic trends, aqueous solution chemistry and redox properties, the range of coordination numbers shown by second and third row metals, electronic spectra and magnetic properties, metal-metal bonding, triple and quadruple bonds, bridging ligands, pi donar ligands in which metal-metal bonding is important, and polyoxometallates. The volume also contains a detailed guide for further...

This book provides a basic introduction to metal-metal bonded carbonyl dimers and clusters and covers their structures and syntheses. It discusses localized bonding schemes and their limitations, and provides an introduction to bonding schemes appropriate for clusters. It also offers an introduction to derivatives, including hydrides, phosphine derivatives, dimers and clusters with organic ligands, and clusters containing units with p-block elements, including interstitial atoms. The final section of the book provides problems which can be used to test readers' knowledge of the principles as...