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The aim of the present work is to design and synthesize some new nitrogenous naphthoquinone, -lapachone analogues, binary, fused, and spiro ring compounds moiety which incorporate heterocyclic moieties of anticipated biological value. Thus, in light of the aforementioned importance of the lawsone compounds, the present work is planned to investigate the reactivity of lawsone and its annulated compounds towards several reagents and conditions. The synthetic compounds have Furthermore, geometrical studies and biological applications of the newly synthesized compounds were implemented. ...