Vibrational Spectroscopy of Molecular Liquids and Solids

ISBN-13: 9781461331131 / Angielski / Miękka / 2013 / 464 str.

Opis

This book has its or1g1n in a NATO Summer School organized from June 25 to July 7 1979, in Menton, France. The purpose of this School was a comparative study of the various aspects of vibra- tional spectroscopy in molecular liquids and solids. This field has been rapidly expanding in the last decade; unfortunately, its development took place independently for liquids and for solids. In these circumstances, the comparison of the basic concepts and techniques used in these two branches of physics appeared as a necessity. The lectures given at the Menton Advanced Study Institute, as well as the exceptionally fruitful and lively discussions which followed them confirmed this point of view. The need of putting together these lectures, in the form of a monograph, clearly appeared during the ASI and the lecturers accepted to write down the material they presented at the Institute, improved thanks to the remarks of the participants. It is the result of this collective work which appears in the familiar Plenum Series.

Spis treści

I Introduction.- Intermolecular Forces.- II Liquids.- Infrared and Raman Study of Vibrational Relaxation in Liquids.- Rotational Spectral Band Shapes in Dense Fluids.- Computer Calculation of Vibrational Band Profiles in Liquids.- Vibrational Relaxation of Hydrogen-bonded Species in Solution: Fine Structure of the ?s(XH) Band.- Experimental Study of Rotational and Vibrational Relaxation in Liquids from Investigation of the IR and Raman Vibrational Profiles.- Collision-Induced Vibrational Spectroscopy in Liquids.- Picosecond Vibrational Spectroscopy.- Vibrational Bandshapes in Viscous Liquids and Glasses.- The Study of Vibrational Relaxation by Ultrasonic and Light Scattering Techniques.- III Solids.- The Dynamics of Molecular Crystals: I. General Theory.- The Dynamics of Molecular Crystals: II. Intermolecular Potentials.- The Dynamics of Molecular Crystals: III. Infrared and Raman Intensity of Lattice Bands.- The Dynamics of Molecular Crystals: IV. Hamiltonian Perturbation Treatment.- Large Amplitude Motions in Molecular Crystals.- Raman and Infrared Lineshapes of Internal Modes in ODIC Phases.- Vibrational Band Shapes of Amorphous Solids.- Order-Disorder Phase Transitions in Solids.- The Effect of Multiphonon Processes on Vibrational Band Shapes in Molecular Solids.- Neutron Spectroscopy Studies on Rotational States in Molecular Solids.- Rotation-translation Coupling in Collective Modes of Molecular Solids and Liquids.- Participants.- Author Index.- Substance Index.