Thermodynamics

ISBN-13: 9781489913753 / Angielski / Miękka / 2013 / 400 str.

N. a. Gokcen;R. G. Reddy

Opis

This edition of Thermodynamics is a thoroughly revised, streamlined, and cor- rected version of the book of the same title, first published in 1975. It is intended for students, practicing engineers, and specialists in materials sciences, metallur- gical engineering, chemical engineering, chemistry, electrochemistry, and related fields. The present edition contains many additional numerical examples and prob- lems. Greater emphasis is put on the application of thermodynamics to chemical, materials, and metallurgical problems. The SI system has been used through- out the textbook. In addition, a floppy disk for chemical equilibrium calculations is enclosed inside the back cover. It contains the data for the elements, oxides, halides, sulfides, and other inorganic compounds. The subject material presented in chapters III to XIV formed the basis of a thermodynamics course offered by one of the authors (R.G. Reddy) for the last 14 years at the University of Nevada, Reno. The subject matter in this book is based on a minimum number of laws, axioms, and postulates. This procedure avoids unnecessary repetitions, often encountered in books based on historical sequence of development in thermodynamics. For example, the Clapeyron equation, the van't Hoff equation, and the Nernst distribution law all refer to the Gibbs energy changes of relevant processes, and they need not be presented as radically different relationships.

Spis treści

Introduction and Definitions. Differential, Integration, and Special Functions. The First Law of Thermodynamics. The Second Law of Thermodynamics. Entropy and Related Functions. Helmholtz and Gibbs Energies. The Third Law of Thermodynamics. Phase Equilibria. Fugacity and Activity. Solutions. Partial (Molar) Properties. Gibbs Energy Change of Reactions. Solutions of Electrolytes. Reversible Galvanic Cells. Phase Diagrams. Special Topics. Appendix I: General References. Appendix II: Tables of Thermodynamic Data for Examples and Problems in Text. Appendix III: Thermodynamic Simulator (TSIM) for Thermodynamic Calculations. Appendix IV: Estimation of Activities in Multicomponent Ionic Solutions. Appendix V: Stability Diagrams. Appendix VI: List of Symbols. Index.