The Chemistry of Hypervalent Halogen Compounds, 2 Volume Set

ISBN-13: 9781119352303 / Angielski / Twarda / 2019 / 1072 str.

Berit Olofsson; Ilan Marek; Zvi Rappoport

Spis treści

1. Fundamental aspects of structure, bonding, and the reactivity of hypervalent iodine compounds 1Halua Pinto de Magalhães, Oliver Sala, and Hans Peter Lüthi2. Structural chemistry of hypervalent iodine compounds 31Michael W. Justik3. Aspects of the chemical energetics of the hypervalent benzene-based organohalogen halosyl, halyl, and perhalyl species 119Maja Ponikvar-Svet Joel F. Liebman4. Mass spectrometry and gas-phase ion chemistry of hypervalent halogen compounds 141Richard A. J. O'hair5. NMR of hypervalent iodine compounds 187Yichen Wu and Alexandr Shafir6. Synthesis of hypervalent iodine compounds for oxidation reactions 221Viktor V. Zhdankin7. Oxidation of alcohols and amines 261Muhammet Uyanik and Kazuaki Ishihara8. Oxidative heteroatom-heteroatom bond formation 307Luis Bering and Andrey P. Antonchick9. Carbon-heteroatom bond formation mediated by hypervalent iodine 365Rafael M. Romero and Kilian Muñiz10. Halogenation and perfluoroalkylation chemistry using hypervalent halogen compounds 409Dmitry Katayev, Benson Jelier, and Antonio Togni11. Arylations promoted by hypervalent iodine reagents 461Piret Villo and Berit Olofsson12. Alkynylations and vinylations 523Durga Prasad Hari, Stefano Nicolai, and Jerome Waser13. Oxidative C.C bond formation (couplings, cyclizations, cyclopropanation, etc.) 581Toshifumi Dohi and Yasuyuki Kita14. Rearrangements and fragmentations mediated by hypervalent iodine reagents 665Sarah E. Wengryniuk, and Sylvain Canesi15. Industrial applications 707Tatsuo Kaiho and Viktor V. Zhdankin16. Hypervalent iodine compounds as precursors for biomedical radiotracers 721Sanjay Telu, Fabrice G. Siméon, Shuiyu Lu and Victor W. Pike17. Chemistry of hypervalent bromine 781Kazunori Miyamoto18. Stereoselective reactions 807Fateh V. Singh and ThomasWirth19. Photochemistry of hypervalent iodine compounds 855Kunfang Jia and Yiyun Chen20. Electrochemistry of hypervalent iodine compounds 897Robert Francke, Timo Broese, and Arend F. Roesel21. Transition metal-catalyzed reactions with iodine(III) reagents 919Gergely L. Tolnai, Zsombor Gonda, and Zoltán NovákSubject index 987

O autorze

Professor Berit Olofsson, Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden.Professor Ilan Marek, Department of Chemistry Technion - Israel Institute of Technology, Haifa, Israel.Professor Zvi Rappoport, Institute of Chemistry The Hebrew University of Jerusalem, Jerusalem, Israel.