Surface Chemistry in Biomedical and Environmental Science

ISBN-13: 9781402047398 / Angielski / Twarda / 2006 / 443 str.

Jonathan P. Blitz; Vladimir Gun'ko

Opis

There exists great hope throughout the scientific community for the application of nanotechnologies to solve myriad technological and societal problems. Nanomaterials and nanoparticles exhibit unique properties which are now being explored for potential uses, as well as hazards. In September 2005 a NATO Advanced Research Workshop convened in Kiev to discuss the current state of the art in surface chemistry and nanomaterials research, with a view towards biomedical and environmental applications. This volume represents the fine work presented at this workshop, consisting of a unique mixture of reviews as well as primary research articles from leading laboratories in Eastern and Western Europe as well as the US. A common theme throughout much of this volume involves adsorption and interfacial behavior of nanomaterials including core-shell particles, nanoparticles derived from oxides, mixed oxides, carbon, carbon/oxide hybrids, functionalized nanoparticles, polymeric biomaterials, and more. The behavior and design of these nanomaterials for adsorption (or sometimes the lack thereof) of toxins, pollutants, narcotics, warfare agents and various biomolecules are studied with a mix of experimental and theoretical approaches. This volume holds a special niche in describing the current state of the art in the fundamentals and applications of a variety of nanomaterials.

Spis treści

Contents. Preface. List of Contributors. Fundamentals. 1. Water structuring at colloidal surfaces; M. Chaplin .- Microgels and core-shell particles; B.Vincent.- Microencapsulation: fundamentals, methods and applications; D. Poncelet.- The molecular layering method: progress in science and practical works for creation of functional nanomaterials; A.A.Malygin.- Analysis of surface structures using XPS with external stimuli; G. Ertas, S. Suzer.- Modification and coating of polymer surfaces; O. Gershevitz et al.- Is it possible to generalize the problems of porous materials formation, study and exploitation?; M. S. Mel’gunov, V. B. Fenelonov.- Theoretical analysis of surface pressure of monolayers formed by nano-particles; V.B. Fainerman et al.- Oxide, carbon, and carbon/mineral adsorbents for toxic, explosive, and narcotic compounds — synthesis, properties, and applications; V. Gun’ko, et al.- Porous polymeric nanocomposites filled with chemically modified fumed silicas; Y. Bolbukh et al.- Ion-electrostatic interaction in systems of inorganic nanoparticles and biological cells in electrolyte solution; L. G. Grecbko et al.- Structural and adsorption characteristics of pyrocabon-mineral adsorbents; J. Skubiszewska-Zieba et al.- Synthesis and structural/adsorption characteristics of unmodified and modified hybrid carbon/mineral adsorbents; J. Skubiszewska-Zieba et al.- Biomedical Applications of Nanomaterials. Surface Functionalization for Biomedical Applications; H.J. Mathieu et al.- Surface modifications to influence adhesion of biological cells and adsorption of globular proteins; W.Norde.- Fundamentals of nanosilica applications for human protection; V. M. Gunko et al.- Medical aspects of application of highly disperse amorphous silica; A. Chuiko et al.- The interaction of nanostructured biomaterials with human cell cultures. The choice of cell cultures for use as biocompatability probes; S. L. James et al.- Physical characterisation of a polycaprolactonetissue scaffold; P. V. Grant et al.- Nanostructured and nanocomposite hydrogels for biomedical applications; A. Spanoudaki et al.- An overview on the toxicity of inhaled nanoparticles; B. Fubini et al.- Detection of V-type nerve agent degradation products using a polypyrrole/pyrroloquinoline quinone-modified electrode; 0. V. Shulga, C. Palmer.- Biological applications of functionalized carbon nanoparticles; J. Barkauskas.- Interaction of cells with nanoparticles; V. A. Pokrovskiy et al.- The role of nature and structure of surface sites in the biological response to silica particle; I. Fenoglio et al.- Magnetically sensitive nanocomposites for medical and biological applications; P. P. Gorbik et al.- Hydrophobized silica nanocomposites with immobilized antioxidants (vitamins C and E); P. Kuzema et al.- Interaction of some biomolecules with modified nanosilica surfaces studied by quantum chemistry; O. Tsendra et al.- Environmental Applications of Nanomaterials.. Synthesis and characterization of ordered mesoporous materials for removal of heavy metal ions; M. Jaroniec, O. Olkhovyk .- Functionalized surfaces: silica structure and metal ion adsorption behavior; I. P. Blitz et al.- Heterogeneously catalyzed alkane isomerization — towards 100 % selectivity; H. Knozinger.- Low temperature oxidation of carbon monoxide over alkali-metal promoted palladium-tin oxide catalysts; B. Mirkelamoglu, G. Karakas.- Nanoparticles of aluminium salts hydrolysis products in water treatment and disinfection; S. Barany et al.- Co-adsorption of the low molecular carboxylic acids and cadmium ions at the metal oxide I electrolyte interface ; w. Janusz, M. Matysek .-Interaction of Phenolic Pollutants with PNIPA hydrogels; K. László et al.- Nanoscale oxides as destructive sorbents for halogenated hydrocarbons; A. M. Volodin et al.-Dynamic adsorption of tert-butylbenzene, cyclohexane and water vapours on fixed activated carbon/molecular sieve beds; D. Palijezuk et al.- Influence of