Solution Behavior of Surfactants: Theoretical and Applied Aspects Volume 2

ISBN-13: 9781461334965 / Angielski / Miękka / 2011 / 822 str.

K. L. Mittal; E. J. Fendler

Opis

This and its companion Volume 1 comprise the proceedings of the International Symposium on "Solution Behavior of Surfactants - Theoretical and Applied Aspects" organized under the auspices of the 11th Northeast Regional Meeting of the American Chemica1 So ci- ety held in Potsdam, N. Y., June 30-July 3, 1980. This ?J Ilposiumre- presented the third event in the se ries of symposia dealing with the topic of surfactants in solution. The first Symposium was held in Albany, N. Y., in 1976 under the title "Micellization, Solubili- zation and Microemulsions"'1the proceedings of which have been doc- umented in a two-volume set - The second was held under the title "Solution Chemistry of Surfactants" in 1978 in Knoxville, TN, an the proceedings of this event have also been properly chronicled - Apropos, the fourth biennial Symposium in this series is entitled "International Symposium on Surfactants in Solution" (K. L. Mittal and B. Lindman, Cochairmen) and is scheduled to be held from June 27 to July 2, 1982 in Lund, Sweden. Since these biennial events have been very successful and important in bringing researchers with varied interests together and in stimulating interdisciplinary communication, so the plans are to continue these on a regular basis with a change in venue for each meeting.

Spis treści

of Volume 2.- III: Micelles in Non-Aqueous Media.- Structure, Solubilizing Properties and Catalysis by Reversed Micelles.- Control of Reactions in Extremely Restricted Environment Provided by Reversed Micelles.- The Surface Chemistry and Solution Behavior of Dinonylnaphthalene Sulfonic Acid - Recent Advances.- Kinetic Concepts in Reversed Micellar Systems.- Photon Correlation Spectroscopy of Inverted Micellar Aggregates of AOT in Heptane.- Observation of Amphiphilic Association in Nonaqueous Solvents by Exclusion Chromatography.- The Effect of Inverse Micelles on the Inter- and Intramolecular Esterification Reactions of an ?-Hydroxyalkanoic Acid.- Transition State Structure for the Reversible Hydration of 1,3-Dichloroacetone in the Presence of Aerosol-OT Reversed Micelles in Hexane.- Discussiom.- IV: Solubilization Phenomenon.- Micellar Solubilization of Enzymes in Hydrocarbon Solvents.- Solubilization in Aqueous Micellar Solutions Studied by NMR-Methods.- Solubilization of Petroleum Oils by Micelle Forming Surfactants.- Non-Solubilization of Corn Oil in Aqueous Surfactant Solutions.- Discussion.- V: Reactions in Micelles and Micellar Catalysis.- The Quantitative Analysis of Micellar Effects on Chemical Reactivity and Equilibria: An Evolutionary Overview.- Reactive Counterion Surfactants.- Stereoselectivity in Micellar Esterolysis.- Selective Mercuration of Dienes in Micellar Medium: Mechanism and Potential Synthetic Application.- Micellar Effects on the Reaction of Ethyl Violet Carbocation with Hydroxide Ion.- The Action of a Surfactant upon Phosphorylase Kinase.- Spectral Study of Aromatic Carboxylic Acids in Micellar Environments.- Micelle Stabilized Room Temperature Phosphorescence.- Micellar Effects on the Radiation Chemistry of Biologically Important Compounds.- Influence of Micellar Microenvironments on Redox and Kinetic Properties of Radical Ions.- Alkaline Hydrolysis in Micellar Sodium Dodecyl Sulfate: The “Binding” of OH to Anionic Micelles.- A Quantitative Treatment of the Deprotonation Equilibria of Benzimidazole in Basic Solutions of Cetyltrimethylammonium Ion (CTAX) Surfactants.- Specific Role of Functional Micelles in the Catalysis of an Elimination Reaction.- Cyclodextrins as Enzyme Models.- Discussion.- VI: Microemulsions and Reactions in Microemulsion Media.- Dynamics of Microemulsions.- Water-in-Oil Microemulsions: Structural Features and Application as Biological Models.- Chemistry of Detergentless Microemulsions.- Vectorially Photoinduced Electron-Transfer Processes across Water-in-Oil Interfaces of Microemulsions.- Discussion.- VII: Use of Surfactants in Analytical Chemistry.- Chelating Behavior of Pyrocatechol Violet with Micelle Forming Cationic Surfactant.- Use of Micellar and Cyclodextrin Solutions in Liquid Chromatographic Separations.- Probing the Mechanism of Micellar Sensitization of Photometric Analysis.- Nonionic Surfactants in Photometric Determination of Trace Metals.- Discussion.- VIII: Miscellaneous Applications of Surfactants.- Surfactants in Particle Migration Imaging.- Polymeric Flocculants and Selective Flocculation - An Overview.- Pesticide Surfactant Systems: A Multiplicity of Surfactant Physical Properties Employed to Improve the Biological Effect.- Deinking of Wastepaper — An Overview.- Surfactant-Polymer Interactions in Tertiary Oil Recovery.- Relationship of Oil Recovery Activity to Surfactant Aggregate Size in Petroleum Sulfonate Solutions.- IX: General Papers.- A Phosphorus-31 NMR Study of Monovalent Cation Interactions with the Negatively Charged Surface of Phosphatidylserine Vesicles.- Lysosomotropic Agents II. Synthesis and Cytotoxic Action of Lysosomotropic Detergents.- Osmotic Coupling: The Key to Faster Mass Transport Experiments.- Kinetics and Equilibria of Na:Ca:Mg Exchange in Zeolite A.- Protection of TrichodermaReesei Cellulase from Inactivation Due to Shaking.- Effect of Decylmethyl Sulfoxide on Skin Penetration.- Discussion.- About the Contributors.