Solubility in Supercritical Carbon Dioxide

ISBN-13: 9780849342400 / Angielski / Twarda / 2006 / 958 str.

Ram B. Gupta; Jae-Jin Shim

Opis

Supercritical fluid extraction is an environmentally safe and cost-effective alternative to traditional organic solvents. Carbon dioxide is widely used as the solvent of choice for applications such as caffeine and nicotine extraction due to its mild critical temperature, nontoxicity, nonflammability, and low cost. Introducing the most complete collection of supercritical CO₂ solubility data currently available, Solubility in Supercritical Carbon Dioxide features experimental data on more than 780 solutes in consistent units and an easily accessible format. This book reflects the authors painstaking efforts to compile solubility data for an extensive variety of compounds including liquids, solids, polymers, foods, drugs, nutraceuticals, pesticides, dyes, and metal complexes. Each of the more than 1200 tables is arranged in alphabetical order by compound, includes a graphical plot of its data, and features the following information:

• Compound name, molecular formula, and molecular weight
• Temperature and pressure given in Kelvin and bar, respectively
• Name and amount of cosolvent, if applicable
• Molar or mass solubility, when applicable
• Mole- or mass-fraction solubility
• Synonyms for the compound, where available
• Reference source for the data

Density data for CO₂ appears in one appendix, while a complete list of solutes by molecular formula appears in the other. Clear, consistent, and carefully organized, Solubility in Supercritical Carbon Dioxide is the most convenient quick-lookup guide for reliable data."

Spis treści

Abbreviations
Solubility
Molecular Weight
Nomenclature
Other
List of Solutes
Introduction
Supercritical Carbon Dioxide
Solubility in Supercritical Carbon Dioxide
Measurements of Solubility in Supercritical Carbon Dioxide
Static Methods
Dynamic Methods
Modeling of Solubility in Supercritical Carbon Dioxide
References
Solubility Data
Acenaphthene through Azobenzene
Barium bis(hexafluoroacetylacetonate) through tert-Butyl-salen
Cafestol through Cyproterone Acetate
DDT through Dotriacontane
Eflucimibe through Ewe's Milk Fat
Fenchone through Fungal Oil
Gallium tris(acetylacetonate) through Griseofulvin
Heneicosane through 1-Hydroxyxanthone
Imipramine Hydrochloride through Iron tris(2,2,7-trimethyl-3,5-octanedionate)
Jojoba Bean Oil
Ketoprofen through Krytox Picolyl Amine
Lactic Acid through Lithium Acetylacetonate
Mandelic Acid through Myristic Acid
Naphthalene through 1-Nonanol
Octacosane through Orange Peel Oil
Palladium bis(acetylacetonate) through Pyrocatechol
Quercetin through p-Quinone
Rape Seed Oil through Rosemary Oil
Salen through Syringic Acid
Taxol through Turmeric Oil
1-Undecanol through Uranyl Dinitrate—Tributyl Phosphate Complex
Vanillic Acid through Vitamin K₃
Water through Wool Wax
2,5-Xylenol through D-Xylose
Yttrium tris(acetylacetonate) and Yttrium tris(hexafluoroacetylacetonate)
Zinc bis(acetylacetonate) through Zopiclone
Appendix A: Density of Carbon Dioxide
Appendix B: List of Solutes by Molecular Formula

O autorze

Ram B. Gupta, Jae-Jin Shim