Small-Scale Synthesis of Laboratory Reagents with Reaction Modeling

ISBN-13: 9780367383046 / Angielski / Miękka / 2019 / 240 str.

Leonid Lerner

Opis

The in-lab preparation of some chemical reagents provides a number of advantages over purchasing commercially prepared samples. This volume contains a detailed description of methods for the rapid and reliable synthesis of many useful reagents that can be difficult to obtain. It provides spectroscopic analyses of products, presents the thermodynamic/kinetic data of reactions, and offers a thorough analysis of the purity of the final products. An additional feature is the mathematical modeling of reactions, some for the first time, with a comparison to the experiment. Enhanced by useful diagrams and photographs, this text is a valuable reference for researchers in small or remote laboratories.

Spis treści

Safety in the Laboratory. Sodium. Potassium. Lithium. Cesium. Lithium Hydride and Sodium Hydride. Bromine. Aluminum Bromide. Lithium Aluminum Hydride. Triethylaluminum and Diethylaluminum Bromide. Hydrazine Sulfate and Alcoholic Hydrazine Hydrate. Sodium and Potassium Azide. Potassium t-Butoxide and Potassium Hydride. Carbon Disulfide. Chlorine. Carbon Tetrachloride. Bis-Trichloromethyl Carbonate (Triphosgene). Phosphorus Pentachloride. Phosphorus Oxychloride. Sulfur Trioxide and Oleum. Thionyl Chloride and Chlorosulfonic Acid. Appendix: Assay of Reagents.

O autorze

Graduating with a BSc (Hons.) in 1984 and a MSc in 1985 from the Victoria University of Wellington, Leonid Lerner obtained his PhD in physics from Cambridge University, UK, in 1989. From 1990–1993 he was a postdoctoral fellow at the Optical Science Centre and Laser Physics Centre of the Australian National University (ANU), and a lecturer in Physics ANU 1994–1996. Leonid has worked in a number of different fields in the natural sciences and has published in a range of scientific disciplines. Currently he is a research scientist at the Defence Science and Technology Organisation, Adelaide, and Honorary Fellow at the School of Chemical and Physical Sciences, Flinders University, Adelaide.