Silicone Resins and their Combinations

ISBN-13: 9783866308282 / Angielski / Twarda / 2014 / 112 str.

Wernfried Heilen; Sascha Herrwerth

Opis

Get a concentrated overview of the chemistry and technology of silicone resins and a deep insight into their use from an industrial point of view: this completely revised and expanded edition reports on most recent developments and points out the outstanding properties of silicones for coatings. Essential for any formulator of competitivemodern paint systems!

Spis treści

1 Introduction 111.1 Organo-siloxanes and organo-polysiloxanes 111.2 Chlorosilanes - the building blocks for silicone resins 171.3 Manufacture of the resin intermediates 202 Silicone resins 232.1 Pure silicone resins 232.1.1 Methyl-silicone resins 262.1.2 Methyl/phenyl-silicone resins 282.2 Silicone combination resins/silicone resin hybrids 292.2.1 Silicone-modified polyester resins 312.2.2 Silicone-modified alkyd resins 312.2.3 Silicone-modified epoxy resins 342.2.4 Silicone-modified polyacrylate resins 382.3 Alkoxy-silyl modified resins and alkoxy-silyl modified isocyanate crosslinkers 392.4 Radiation-curable silicone resins 412.4.1 Acrylic-functional silicone resins 412.4.2 Epoxy-functional silicone resins 452.5 Room temperature vulcanizing silicone resins (RTV resins) 462.6 Waterborne silicone resins 483 Examples of applications of silicone resins 513.1 Silicone resins for heat resistant coatings and corrosion protection above 300 °C 513.2 Silicone-modified aromatic polyester resins for heat resistant coatings up to 250 °C for decorative coatings 563.3 Applications at normal temperatures 593.3.1 Silicone-modified aliphatic epoxy resin for versatile coating applications 593.3.2 Acrylic- and epoxy-functional silicone resins as UV-cured release coatings 653.4 Silicones and silicone resins in building conservation 693.4.1 External water repellency 693.4.2 Internal water repellency 753.4.3 Architectural coatings 773.4.4 Silicate emulsion coatings and renderings 783.4.5 Emulsion based coatings with silicate character (SIL coatings) 803.4.6 Siloxane architectural coatingswith strong water-beading effect 813.4.7 Silicone resin coatings and renderings 823.4.8 Below-critical PVC formulated exterior coatings 873.4.9 Photocatalytic architectural coatings 874 Outlook 915 Glossary 935.1 Façade protection theory according to Künzel 935.2 sd-value 935.3 w-value 955.4 Definitions of PVC and CPVC 976 Analysis of silicone polymers 996.1 NMR spectroscopy 996.2 IR spectroscopy 1036.3 Wet analysis 1037 Literature 105Authors 108Index 109