Oxygen Ion and Mixed Conductors and Their Technological Applications

ISBN-13: 9789048154340 / Angielski / Miękka / 2011 / 475 str.

H. L. Tuller; Joop Schoonman; Ilan Riess

Opis

Progress in the development of oxygen ion and mixed conductors is responsible for innovations in gas sensors, fuel cells, oxygen permeation membranes, oxygen pumps and electrolyzers. Commercialization has been impeded by material stability and compatibility issues, high fabrication costs and an inadequate understanding of the interfacial phenomena controlling the operation of the devices. Here, a group of experts cover all the key topical areas, ranging from fundamentals relating to (a) defects, electrochemical and interfacial processes, (b) catalysis, electrocatalysis and gas reforming, to design and fabrication, including (c) advanced electroceramic processing methods, (d) materials selection and optimization, (e) and applications including scale-up, commercialization and competitive technologies. Readership: Materials scientists, chemists, physicists and chemical and electrical engineers, either first entering the field or active within it.

Spis treści

Fundamentals. Solid State Electrochemical Cells; I. Riess. Electrode Processes in Solid Oxide Fuel Cells; I. Riess. Defects and Transport: Implications for Solid Oxide Electrolytes and Mixed Conductors; H.L. Tuller. Interfaces; J. Maier. Electrocatalysis, Catalysis and Electrochemical Promotion in Solid Electrolyte Cells; C.G. Vayenas, S.I. Bebelis. Processing, Materials Selection and Optimization. Fabrication Processes for Electroceramic Components; J. Will, et al. Materials Design and Optimization; H.L. Tuller. Chemical Spray Deposition of Ceramic Films; P. Bohac, L.J. Gauckler. Electrostatic Spray Deposition (ESD) - A Novel Technique for Ceramic Thin Film Fabrication; C. Chen, J. Schoonman. Dense Ceramic Ion Conducting Membranes; B.C.H. Steele. Thermal and Isothermal Expansion; A. Bieberle, L.J. Gauckler. Temperature Limitations in the Processing Sequence of Solid Oxide Fuel Cells; C. Kleinlogel, L.J. Gauckler. Metallic Interconnector; A. Bieberle, L.J. Gauckler. Glass Seals; A. Bieberle, L.J. Gauckler. Applications, Commercialization and Competitive Technologies. Electrochemical Sensors; J. Maier. Solid Oxide Fuel Cells; B.C.H. Steele. Comparison of Solid Oxide Fuel Cells with Alternative Fuel Cells and Competitive Technologies; M. Mogensen.