Organometallics in Organic Synthesis 2: Aspects of a Modern Interdisciplinary Field

ISBN-13: 9783540505310 / Angielski / Miękka / 1989 / 322 str.

Helmut Werner; Gerhard Erker

Opis

Organic Synthesis via Organometallics is an interdisciplinary project sponsored by the Volkswagen Stiftung to stimulate research and discussion of advances in the field. To improve international communication, leading experts are invited to regular symposia. In this volume, 17 lectures presented at the second symposium in W rzburg, October 1988, are collected. From the topics covered it complements the previous volume, edited by A. de Meijere and H. tom Dieck.

Spis treści

Organic Syntheses via Organometallics.- Diazadiene-Controlled C-C Coupling Reactions on Palladium and Iron.- Highly Reactive ?-Arene Iron Complexes and Their Use in Stoichiometric and Catalytic Cyclic Addition Reactions.- Stereochemistry of Arenetricarbonylchromium Complexes — Useful Intermediates for Stereoselective Syntheses.- Ironcarbonyl Complexes of Exocyclic Polyenes. The Tricarbonyl(1,3-diene)iron Moiety as Remote Substituent.- Metal-Induced Dimerisations of Cyclic Diacetylenes.- Novel Catalytic Applications of Ruthenium Clusters.- Selective Organic Synthesis by Diene Complexes of Early Transition Metals.- Metallacyclobutanes: Synthons and Catalysts.- New Properties of Reagents by Complexation of Carbanions on Transition-Metals: Which Metal is in Each Case the Most Favorable One?.- Organometallic Transformations via C-H Bond Activation.- Remote Functionalization of Carbon-Hydrogen and Carbon-Carbon Bonds by Bare Transition Metal Ions in the Gas Phase.- Aktivierung von Mehrfachbindungssystemen auf Clustern.- Directed — and Undirected — Syntheses of Novel Organic Compounds via Iron, Cobalt and Chromium Complexes.- Enantioselective Synthesis of Organic Compounds with Optically Active Transition Metal Catalysts and Transition Metal Compounds.- Diolefin Iron Complexes — Useful and Versatile Tools in Organic Synthesis.- Donor-Acceptor-Substituted Cyclopropanes via Fischer Carbene Complexes.