Organic Syntheses, Volume 99

ISBN-13: 9781394200863 / Angielski / Twarda / 2023 / 400 str.

Richmond Sarpong

Opis

The current volume continues the tradition of the Organic Syntheses series, providing carefully checked and edited experimental procedures that describe important synthetic methods, transformations, reagents, and synthetic building blocks or intermediates with demonstrated utility in organic synthesis. These significant and interesting procedures should prove worthwhile to many synthetic chemists working in increasingly diverse areas. A trusted guide for professionals in organic and medicinal chemistry in academia, government, and industries, including pharmaceuticals, fine chemicals, agrochemicals, and biotechnological products.

Spis treści

Chapter 1 Synthesis of [(R)-DTBM-SEGPHOS]NiCl2 for the Enantioselective Acetal Formation from N-Propanoyl-1,3-Thiazinane-2-thione and Trimethyl OrthoformateChapter 2 Synthesis of Alkylboronic Esters from Alkyl IodidesChapter 3 Preparation of N-Formylamides by Oxidative Cleavage of N-AcylaminoacidsChapter 4 Transition-Metal-Free Synthesis of an Aryl Boronate Ester through Base-Mediated Boryl Substitution of an Aryl Halide with a SilylboraneChapter 5 A Convenient Method for the Removal of Tetrabutylammonium Salts from Desilylation ReactionsChapter 6 Discussion Addendum for: Asymmetric Michael Reaction of Aldehydes and NitroalkenesChapter 7 Preparation of a Donor-Acceptor Stenhouse Adduct (DASA): 5-((2Z,4E)-5-(Diethylamino)-2-hydroxypenta-2,4-dien-1-ylidene)-2,2-dimethyl-1,3-dioxane-4,6-dioneChapter 8 Preparation of MIDA Anhydride and Reaction with Boronic AcidsChapter 9 Discussion Addendum for: Preparation of 1,1-Difluoroallenes by Difluorovinylidenation of Carbonyl CompoundsChapter 10 Ethoxypillar[6]areneChapter 11 Organocatalytic Dimerization of SuccinaldehydeChapter 12 Synthesis of Phenanthridinones via the Palladium-Catalyzed Annulation of BenzyneChapter 13 Synthesis of Triphenylene via the Palladium-Catalyzed Annulation of BenzyneChapter 14 Synthesis of (((1R,3S,3'S)-3,3'-Diethyl-3H,3'H-1,1'-spirobi[isobenzofuran]-7,7'-diyl)bis(oxy))bis(diphenylphosphane)Chapter 15 Discussion Addendum for: Nickel-Catalyzed Cross-Coupling of Aryl Halides with Alkyl Halides: Ethyl 4-(4-(4-methylphenylsulfonamido)-phenyl)butanoateChapter 16 Discussion Addendum for: Detrifluoroacetylative Diazo Group Transfer: (E)-1-Diazo-4-phenyl-3-buten-2-oneChapter 17 Preparation of 9-Azabicyclo[3.3.1]nonane-N-oxyl (ABNO)Chapter 18 Discussion Addendum for: Synthesis of N-Boc-N-Hydroxymethyl-L-phenylalaninal and Methyl trans-Oxazolidine-5-carboxylate, Chiral Synthons for threo-ß-Amino-alpha-hydroxy AcidsChapter 19 Large Scale Oxidative Cyclization of (E)-Hex-3-en-1-yl(4-Methoxyphenyl)sulfamateChapter 20 Synthesis of Carboxylic Acids from Benzamide Precursors Using Nickel CatalysisChapter 21 Stereoselective Synthesis of Dimethyl 4(S)-Allyl-N-Boc-L-glutamate and Related CongenersChapter 22 Discussion Addendum for: Preparation of Diisopropylammonium Bis(catecholato)cyclohexylsilicateChapter 23 Preparation of 1,2:5,6-Di-O-cyclohexylidene-D-mannitol and 2,3-Cyclohexylidene-D-glyceraldehydeChapter 24 Transformation of a N,N-Dimethylaniline N-oxide into a Tetrahydroquinoline Scaffold via a Formal Polonovski-Povarov ReactionIndex