Nonmolecular Solids, Volume 30

ISBN-13: 9780471305088 / Angielski / Twarda / 1995 / 328 str.

Leonard V. Interrante; Donald W. Murphy

Opis

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Spis treści

Chapter One BINARY COMPOUNDS.

1. Tungsten Dichloride.

2. Zirconium Monochloride and Monobromide.

3. Lanthanum Triiodide (and Other Rare–Earth Metal Triiodides).

4. Lanthanum Diiodide.

5. Rare–Earth Sesquisulfides, Ln₂S₃.

6. Group IV Sulfides.

7. Titanium Disulfide.

8. Metathetical Precursor Route to Molybdenum Disulfide.

9. Lithium Nitride, Li₃N.

10. Aluminum Nitride.

11. Electrochemical Syntheses of Binary Silver Oxides.

12. Trisodium Heptaphosphide and Trisodium Undecaphosphide.

Chapter Two TERNARY COMPOUNDS.

13. Lead Ruthenium Oxide, Pb₂[Ru_2–xPb⁴⁺_x]O_6.5.

14. Calcium Manganese Oxide, Ca₂Mn₃O₈.

15. Ternary Chlorides and Bromides of the Rare–Earth Elements.

16. Cesium Scandium(II) Trichloride.

17. A One–Dimensional Polychalcogenide, K₄Ti₃S₁₄.

18. Synthesis of K₄M₃Te₁₇ (M = Zr, Hf) and K₃CuNb₂Se₁₂.

19. Synthesis of Ternary Chalcogenides in Molten Polychalcogenide Salts: –KCuQ₄, KAuS₅, NaBiS₂, KFeQ₂ (Q = S, Se).

Chapter Three CRYSTAL GROWTH.

20. Single Crystals of Transition–Metal Dioxides.

21. Molybdenum(IV) Oxide and Tungsten(IV) Oxide Single Crystals.

22. Niobium Monoxide.

23. Barium Titanate, BaTiO₃.

24. Bismuth Titanate, Bi4Ti₃O₁₂.

25. Sodium Tungsten Bronzes.

26. Potassium Molybdenum Oxide "Blue Bronze": K_0.30MoO₃.

27. Growth and Characterization of Single Crystals of Zinc Ferrites, Fe_3–xZn_xO₄.

28. Congruent Growth of Single–Crystal La₂NiO₄ and Other Layered Nickelates by Radiofrequency Skull Melting.

29. Hydrothermal Synthesis and Crystal Growth of Potassium Titanyl Arsenate. KTiOAsO4.

30. Synthesis of La₂Ta₃Se₂O₈ Single Crystals.

Chapter Four INTERCALATION COMPOUNDS.

31. The Alkali Ternary Oxides, A_xCoO₂ and A_xCrO₂ (A = Na, K).

32. Tantalum Disulfide (TaS₂) and Its Intercalation Compounds.

33. Ammonia Solvated and Neat Lithium–Titanium Disulfide Intercalates.

34. Intercalation Compounds with Organic –Donors: FeOCl(TTF)_1/8.5, FeOCl(TSF)_1/8.5, and FeOCl(Perylene)_1/9.

35, Layered Intercalation Compounds.

36 . Lithum Insertion Compounds.

Chaper Five OXIDE SUPERCONDUCTORS AND RELATED COMPOUNDS.

37. Synthesis of Superconducting Oxides.

38. Synthesis of Tl₂Ba₂Ca_n–1Cu_nO_2n+4 (n = 1,2,3), (Tl, M) Sr₂CuO_5+/– (M = Bi, Pb), and (Tl, Pb) Sr₂CaCu₂O_7+/– .

39. Preparation of Ba₄BiPb₂TlO₁₂, a 10.7 K Superconductor.

40. Barium Yttrium Copper Oxide Crystals.

41. Synthesis of the Perovskite Series LaCuO_3– .

42. Lithium Niobium Oxide: LiNbO₂ and Superconducting Li_xNbO₂.

Chapter Six MISCELLANEOUS SOLID–STATE COMPOUNDS.

43. Zeolite Molecular Sieves.

44. Substituted –Aluminas.

45. Vanadyl Phosphates and Organylphosphonates.

46. Quaternary Chlorides and Bromides of the Rare–Earth Elements: El pasolites A¹₂B¹RE¹¹¹X₆[r(A¹) > r(B¹)].

47. Preparation of Ta₂S₂C.

48. Scandium Strontium Borate, Aluminum Strontium Yttrium Borate, and Lanthanum Magnesium Strontium Borate.

49. Preparation of ZrO₂, ZnO, and ZnS Thin Films.

Contributor Index.

Subject Index.

Formula Index.

Chemical Abstracts Service Registry Number Index.