NMR and Chemistry: An Introduction to Modern NMR Spectroscopy, Fourth Edition

ISBN-13: 9781138410237 / Angielski / Twarda / 2017

J.W. Akitt

Opis

Keeping mathematics to a minimum, this book introduces nuclear properties, nuclear screening, chemical shift, spin-spin coupling, and relaxation. It is one of the few books that provides the student with the physical background to NMR spectroscopy from the point of view of the whole of the periodic table rather than concentrating on the narrow applications of 1H and 13C NMR spectroscopy. Aids to structure determination, such as decoupling, the nuclear Overhauser effect, INEPT, DEPT, and special editing, and two dimensional NMR spectroscopy are discussed in detail with examples, including the complete assignment of the 1H and 13C NMR spectra of D-amygdain.

The authors examine the requirements of a modern spectrometer and the effects of pulses and discuss the effects of dynamic processes as a function of temperature or pressure on NMR spectra. The book concludes with chapters on some of the applications of NMR spectroscopy to medical and non-medical imaging techniques and solid state chemistry of both I = F1/2 and I > F1/2 nuclei. Examples and problems, mainly from the recent inorganic/organometallic chemistry literature support the text throughout. Brief answers to all the problems are provided in the text with full answers at the end of the book.

Spis treści

The Theory of Nuclear Magnetization. The Magnetic Field at the Nucleus: Nuclear Screening the Chemical Shift. Internuclear Spin-Spin Coupling. Nuclear Magnetic Relaxation. The Spectrometer. Making the Spins Dance. NMR Spectra of Exchanging and Reacting Systems. Multiple Resonance and One-Dimensional Pulse Sequences. Two-Dimensional NMR Spectroscopy. Magnetic Resonance Imaging and Biomedical NMR. High-Resolution Solid-State NMR. Bibliography. Answers to Questions. Index.

O autorze

Akitt, J.W.; Mann, B. E.