Modelling and Numerical Simulations II

ISBN-13: 9781461424444 / Angielski / Miękka / 2012 / 518 str.

Opis

The present volume is the second in a two-volume set dealing with modelling and numerical simulations in electrochemistry. Emphasis is placed on the aspect of nanoelectrochemical issues. It seems appropriate at this juncture to mention the n- growing body of opinion in some circles that George Box was right when he stated, three decades ago, that All models are wrong, but some are useful . Actually, when the statement itself was made it would have been more appropriate to say that All models are inaccurate but most are useful nonetheless . At present, however, the statement, as it was made, is far more appropriate and closer to the facts than ever before. Currently, we are in the midst of the age of massively abundant data. Today s philosophy seems to be that we do not need to know why one piece of information is better than another except through the statistics of incoming and outgoing links between information and this is good enough. It is why, both in principle and in practice, one can translate between two languages, without knowledge of either. While none of this can be ignored, and it may even be true that All models are wrong and increasingly you can succeed without them the traditional approach of scienti?c modelling is still the order of the day. That approach may be stated as hypothesize measure model test. It is in this light that the present volume should be viewed."

This volume is meant as an introductory resource aimed at practitioners of electrochemistry research, technology, and development mainly at the atomic, molecular or macromolecular levels. Thus emphasis is placed at length scales in the 1-100 nm range. The volume will help provide understanding of electrochemical phenomena and materials at the nanoscale through modeling and numeric simulations. It also serves as a means to create and use structures, electrochemically based devices, and systems that possess novel properties and functions because of their small or intermediate sizes.

Recenzje

From the reviews:

"The present book is divided into ten chapters and continues with the high standard, the first part (Modern Aspects of Electrochemistry 43 Modelling and Simulations) already set. ... the present book 'Modern Aspects of Electrochemistry 44 Modelling and Numerical Simulations II' edited by Mordechay Schlesinger continues the high and valuable standard of the series. It is surely worth to become part of the library of researchers and interested professionals in the field of electrochemical modelling and its application on various problems." (T. Eichler, Materials and Corrosion, Vol. 62 (9), 2011)

Spis treści

Numerical Modeling of Certain Electrochemical Processes.- Near-Field Optics for Heat-Assisted Magnetic Recording (Experiment, Theory, and Modeling).- Symmetry Considerations in the Modelling of Light–Matter Interactions in Nanoelectrochemistry.- Applications of Computer Simulations and Statistical Mechanics in Surface Electrochemistry.- AC-Electrogravimetry Investigation in Electroactive Thin Films.- Monte Carlo Simulations of the Underpotential Deposition of Metal Layers on Metallic Substrates: Phase Transitions and Critical Phenomena.- Topics in the Mathematical Modeling of Localized Corrosion.- Density-Functional Theory in External Electric and Magnetic Fields.- Acoustic Microscopy Applied to NanoStructured Thin Film Systems.- Current Distribution in Electrochemical Cells: Analytical and Numerical Modeling.

O autorze

Schlesinger, Mordechay, PhD, is a professor in the Department of Physics at the University of Windsor, Ontario, Canada.

Blurb

MODERN ASPECTS OF ELECTROCHEMISTRY

No. 44

Edited by Mordechay Schlesinger

University of Windsor, Windsor, Ontario, Canada

Topics in Number 44 include:

• The basic mathematical models which arise in some electrochemical processes in regards to galvanic corrosion phenomena
• Near field transducers and their related applications to nano-chemistry and electrochemistry
• How symmetry considerations play a major role in modern scientific computation
• The methods used in the analysis of electrochemical systems, including computer simulations and quantum and statistical mechanics
• The techniques used to investigate ionic and solvent transfer and transport in electroactive materials
• Monte Carlo simulations of the underpotential deposition of metal layers on metallic substrates
• The range of models applied to localized corrosion processes and a review of recent work on the modeling of pitting corrosion
• Descriptions of the conceptual structure of Density-Functional Theory and its practical applications
• Whether scanning acoustic microscopy can be applied to nano-scaled electrochemically deposited thin film systems
• The processes and equations underlying the modeling of the current distribution in electrochemical cells

From reviews of previous volumes:

"This long-standing series continues its tradition of offering high quality reviews of established and emerging subject areas, together with the less common aspects of electrochemical science … Deserves a place in electrochemistry libraries and should prove useful to electrochemists and related workers."

-Chemistry and Industry

"Continues the valuable service that has been rendered by the Modern Aspects series."

- Journal of Electroanalytical Chemistry

"Will definitely be of much use to researchers in the field of electrochemistry… The editors of this well-produced volume deserve all appreciation for maintaining the excellent standard of the series."

- Bulletin of Electrochemistry

"Extremely well-referenced and very readable … Maintains the overall high standards of the series."

- Journal of the American Chemical Society