Micellar Catalysis

ISBN-13: 9781574444902 / Angielski / Twarda / 2006 / 482 str.

Niyaz Mohammad Khan

Opis

Micelles are prevalent in naturally occurring and biological catalytic reactions. However, it is only in recent decades that scientists have developed kinetic models clarifying how micelle-mediated catalysis works at a molecular level. Written by a leading expert in the field, Micellar Catalysis is an in-depth examination of how micelles affect reaction mechanisms and reaction rates in organic and inorganic reactions.
The book first discusses the structural and chemical properties of micelles and the role of thermodynamics, concentration, and additives in forming micelles. Demonstrating how intermolecular forces influence the reaction mechanisms, the author presents kinetic models for reactions catalyzed by normal micelles, as well as mixed micelles and metallomicelles. The book also compares various types of catalytic reactions with and without micelles to quantify their effect on reaction rates and rate constants. Using this information, it illustrates how micelles can modify reaction rates and improve catalytic efficiency, particularly for industrial processes. The final chapter explains the principles of kinetics used for data analysis.
Focused on kinetic, chemical, and physical aspects of micelle-mediated reactions, this book offers clear insight into the complex mechanisms that occur in biological reactions. Micellar Catalysis is an essential source of reference for scientists involved in the research and development of micelles for industrial and biochemical applications.

Spis treści

MICELLES
Normal Micelles
Hemimicelles
Reversed Micelle

CATALYSIS IN CHEMICAL REACTIONS: GENERAL THEORY OF CATALYSIS
Catalysis and Free-Energy Reaction Coordinate Diagram
Mechanistic Change in Catalyzed Reactions
Proximity and Shielding Effects of Catalyst
Classification of Catalysis

GENERAL MECHANISMS OF MICELLAR CATALYSIS: KINETIC MODELS FOR MICELLE-CATALYZED REACTIONS
Preequilibrium Kinetic Model of the Micelle
Pseudophase Model of the Micelle
Berezin's Pseudophase Model
The Multiple Micellar Pseudophase Model
Other Micellar Kinetic Models
Dispersed Medium Model of Micellar Solution

NORMAL MICELLE: EFFECTS ON REACTION RATES
Unimolecular and Solvolytic Reactions
Bimolecular Reactions
Intramolecular Reactions
Effects of Mixed Aqueous-Organic Solvents on Micellar Binding Constants (KS) of Solubilizates
Micelle as Modifier of Reaction Rate

MIXED NORMAL MICELLES: EFFECTS ON REACTION RATES
Unimolecular and Solvolytic Reactions
Bimolecular Reactions

METALLOMICELLES: EFFECTS ON REACTION RATES
Nonfunctional Metallomicelles
Induced Functional Metallomicelles

CHEMICAL KINETICS AND KINETIC PARAMETERS
Introduction
Fundamentals of Chemical Kinetics
Empirical Kinetic Equations
Reaction Mechanism, Theoretical Rate Law, and Theoretical Kinetic Equations
Reliability of Derived or Calculated Kinetic Parameters

APPENDIX A
APPENDIX B

INDEX

*Each Chapter Contains an Introduction Section and References

O autorze

Mohammad Niyaz Khan