Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations

ISBN-13: 9783662156636 / Angielski / Miękka / 2013 / 323 str.

B. Meunier

Opis

This volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species involved in catalytic oxidations. The series contains critical reviews of the present position and future trends, and short and concise reports written by the world's renowned experts.

Spis treści

B. Meunier, J. Bernadou: Active Iron-Oxo and Iron-Peroxo Species in Cytochrome P-450 and Peroxidases; Oxo-Hydroxo Tautomerism with Water-Soluble Metalloporphyrins .- D.L. Wertz, J.S. Valentine: Nucleophilicity of Iron-Peroxo Porphyrin Complexes .- Y. Watanabe, H. Fujii: Characterization of High-Valent Oxo-Metalloporphyrins .- D. Schröder, H. Schwarz, S. Shaik: Characterization, Orbital Description, and Reactivity Patterns of Transition-Metal Oxo Species in the Gas Phase .- P.E.M Siegbahn, R.H. Crabtree: Quantum Chemical Studies on Metal-Oxo Species Related to the Mechanisms of Methane Monooxygenase and Photosynthetic Oxygen Evolution .- J.-J. Girerd, F. Banse, A.J. Simaan: Characterization and Properties of Non-Heme Iron-Peroxo Complexes .- W.B. Tolman, A. Blackman: Copper-Dioxygen and Copper-Oxo Species Relevant to Copper Oxygenases and Oxidases .- F.E. Kühn, W.A. Herrmann: Rhenium-Oxo and Rhenium-Peroxo Complexes in Catalytic Oxidations .- W. Adam, C.M. Mitchell, C.R. Saha-Moeller, O. Weichhold: Structure, Reactivity and Selectivity of Metal-Peroxo Complexes Versus Dioxiranes .- R.M. Burger: Nature of Activated Bleomycin