Metal Nano 3D Superlattices: Synthesis, Properties, and Applications

ISBN-13: 9783527344772 / Angielski / Twarda / 2023 / 448 str.

) Pileni Paris Marie-Paule (Universite P et M Curie

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SYNTHESES OF METAL NANOCRYSTALSNanocrystal Growth Processes and Control of Size and DistributionCrystalline Structure of Metal NanocrystalsVarious Techniques Used to Produce Metal Nanocrystals and Control their Sizes and DistributionInfluence of the Coating Agents on the Size ControlN-Heterocyclic Carbene Ligands for Au Nanocrystals StabilizationConclusionINFLUENCE OF THE NANOPARTICLE CRYSTALLINE STRUCTURES CALLED NANOCRYSTALLINITIES ON VARIOUS PROPERTIES Nano-Kinkerdall Local Surface Plasmon Resonance, LSPR Acoustic Vibrational Modes 3D Superlattice Growth Processes Mechanical Properties Conclusions AU 3D SUPERLATTICES PRODUCED BY SOLVENT EVAPORATION PROCESS 3D Superlattice Morphology of Au Nanocrystal Coated with Thiol DerivativesInterparticle Distance of Nanocrystals in 3D Superlattices Au 3D Superlattices Coated with N-Heterocyclic Carbene Conclusions 3D SUPERLATTICE GROWTH A THERMODYNAMIC EQUILIBRIUMHomogeneous and Heterogeneous 3D Superlattice Growth Processes Submillimeter Size Single 3D Superlattices of 5nm Au NanocrystalsConclusions AG 3D SUPERLATTICESControl of the Crystalline Structure of Ag 3D Superlattices Optical Properties Stability Conclusions MESOSTRUCTURE OF MAGNETIC NANOCRYSTALS Magnetic Nanocrystals Dispersed in Solution: Ferrofluids Mesostructures of Maghemite Nanocrystals Mesostructures of Cobalt NanocrystalsConclusions BINARY 3D SUPERLATTICESStructure of 3D Superlattices Predicted by the Hard Sphere ModelLimitation of the Hard Sphere ModelsSolvent-Mediated Crystallization of Nanocrystal 3D Assemblies of Silver Nanocrystals: Unexpected Superlattice Ripening Collective Properties Involved in Self-Assemblies of Binary SystemsConclusions ANALOGY BETWEEN 3D SUPERLATTICES AND ATOMIC CRYSTALS: CRYSTALLINE STRUCTUREAtomic Crystals, Shaped 3D Superlattices and MineralsNegative 3D Superlattices Vicinal SurfacesQuasi 3D SuperlatticesConclusions ANALOGY BETWEEN 3D SUPERLATTICES AND ATOMIC CRYSTALS: PHYSICAL PROPERTIESMagnetic Properties Longitudinal Acoustic Phonons Breathing ModesConclusions 3D SUPERLATTICE STABILITY Influence of Temperature Edging Process Solvent-Mediated Crystallization of Nanocrystal 3D Assemblies Conclusions INTRINSIC PROPERTIES RELATED DUE TO THE SELF-ASSEMBLIES OF NANOCRYSTALSEpitaxial Crystal Growth as a Result of the Manocrystal OrderingUnexpected Electronic Properties of Micrometer-Thick 3D Superlattices of Au Nanocrystals Collective Magnetic Properties of Co Nanocrystals Self-Assembled in 3D SuperlatticesSuper-Spin Glass Behavior of FCC 3D Superlattices. Alignment of Magnetic NanocrystalsCo 3D Superlattice Collective Properties of Amorphous Nanoparticles ConclusionMECHANICAL PROPERTIES OF 3D SUPERLATTICESMeasurements of Mechanical Properties using Atomic Force Microscope, AFM3D Superlattices Produced under Thermodynamic Processes3D Superlattices Produced through Heteregeneous 3D Superlattice Growth Process Do the Apparent Discrepancies of the Young Moduli Produced with a Large Variety of Metallic Nanocrystals Self-Assembled in fcc Structures Remain Valid or not? Mesoscopic Assemblies of Co Nanocrystals Differing by their Size Distribution: Mechanical Intrinsic Properties. ConclusionsCRACKS IN NANOCRYSTAL FILMCracks of Nanocrystal FilmsCracks in Nature Conclusions WATER DISPERSIVE HYDROPHOBIC SUPRASTRUCTURES: SPECIFIC PROPERTIES Au and Co "Clustered" Structures. Colloidosomes and SupraballsNanoheaters Conclusion NANOCRYSTAL SELF-ASSEMBLY IN CELLS Ferrite Colloidosomes and Supraballs Intracellular Fate of Hydrophobic Nanocrystal Self-Assemblies in Tumor Cells Conclusion PHOTOTHERMAL EFFECTS IN THE TUMOR ENVIRONMENTColloidosomes and SupraballsPhotothermal Properties: Apparent Contradiction Between the Global Heating and Cell DeathPhotothermal Properties in the in Vivo Tumor MicroenvironmentSuprastructures Modulate the Distribution of Fe3O4 Nanocrystals in the Tumor MicroenvironmentPhotothermal Effects on the Tumor Extracellular MatrixConclusion

O autorze

Marie-Paule Pileni is a Distinguished Professor at University P&M CurieSorbonne University and Senior Researcher in Nuclear and Environmental Center, France. She is a member (1999- at present) and chair (2004-2010) of Institut Universitaire de France, IUF, which favors the development of high-quality research and interdisciplinary projects among French universities. Over her career, she has received significant awards and prizes, such as the Langmuir award of the American Chemical Society, the lecture award of the Japanese Chemical Society, Emila Valori Award, French Academy of Sciences, Descartes-Huygens Prize, Royal Netherlands Academy of Arts and Sciences, Doctor Honoris Causa, Chalmers University, Göteberg, Sweden and the research award of the Alexander von Humboldt Foundation in Germany.