Metal Catalysed Reactions in Ionic Liquids

ISBN-13: 9781402039140 / Angielski / Twarda / 2005 / 246 str.

Paul J. Dyson; Tilmann J. Geldbach

Opis

Metal Catalysed Reactions in Ionic Liquids is the first non-edited book on the subject of metal catalyzed reactions in ionic liquids to cover the literature from its origins until early 2005.

Following a general introduction to the field of biphasic/multiphasic catalysis, the book moves on to describe the synthesis, the functionalisation, and fundamental properties of ionic liquids relevant to catalysis. It then analyses the catalysed reactions according to their type, encompassing hydrogenation, hydroformylation, oxidation, C-C coupling reactions, metathesis, dimerisation, polymerisation and more. Trends, generalisations, advantages and disadvantages of ionic liquids for specific reaction types are also examined as well as specific processes such as supported ionic liquid phase catalysis, continuous processes using CO2 extraction and nanoparticle catalysis.

Metal Catalysed Reactions in Ionic Liquids is of interest to those working in catalysis/green chemistry, in particular to advanced level undergraduate and graduate students and researchers in bi- or multiphasic catalysis using ionic liquids.

Recenzje

From the reviews:

"This book is easy to read and explains the physical and chemical properties of ionic solvents in great detail ... . is suitable either for specialists from each of these areas or for students, since the fundamentals of both ionic liquids and metal-catalyzed reactions are covered in sufficient depth. The explanations are easy to understand ... . this monograph offers both students and researchers an eminently readable and concise overview that makes the key fundamentals of 'metal catalysed reactions in ionic liquids' accessible ... ." (www.organic-chemistry.org, June, 2006)

"This volume is the 29th in the well-received series Catalysis by Metal Complexes published by Springer. ... The figures and tables presented throughout the text are clear, accurate, and germane to the discussion. ... the volume is well written and organized. ... would be an excellent choice of text for a graduate course on alternative solvents and is a must read for anyone in or thinking of entering the field ... . I know it will remain within close reach on my bookshelf." (Brian J. Frost, Journal of the American Chemical Society, Vol. 128 (21), 2006)

Spis treści

Introduction: A Brief History of Biphasic Catalysis.- The Importance of Biphasic Catalysis.- The Alternatives to Aqueous-Organic Biphasic Processes.- Key Developments in the Chemistry of Ionic Liquids.- General Properties of Ionic Liquids that Lend Themselves to Catalysis.-References.- Ionic Liquids – Properties and Preparation: Introduction.- Composition and Physical Properties of Ionic Liquids.- Synthesis of Ionic Liquids.- Functionalised Ionic Liquids.- Toxicological and Environmental Concerns.- References.- Hydrogenation: Introduction.- Hydrogen Solubility in Ionic Liquids.- Ionic Liquids in Hydrogenation Reactions.- Ionic Liquids in Hydrogenation Reactions.- Nanoparticle Catalysts.- Supported Ionic Liquid Catalysis. Supported Ionic Liquid Catalysis.-References.- Hydroformylation: Introduction.- Gas and Substrate Solubility in Ionic Liquids .- Hydroformylation in Ionic Liquids.- Ligand Design.- Influence of the Solvent.- Special Processes.- Outlook.- References.- Oxidation Reactions: Oxidants.- Ionic Liquids for Oxidation Reactions.- Oxidation of Alkenes.- Oxidation of Alcohols and Thiols.- Other Oxidation Reactions.- Conclusion.- References.- Carbon-Carbon Coupling Reactions: Introduction.- Catalyst Stability in Ionic Liquid Mediated.- Heck Coupling Reactions.- Other Palladium Catalysed Cross-Coupling Reactions.- Allylic Alkylation.- References.- Olefin Metathesis: Introduction.- General Considerations.- Task-Specific Catalysts.- Ring -Opening Polymerisation.- Concluding Remarks.- References.- Dimerisation – Polymerisation: Dimerisation and Oligomerisation.- Polymerisation.- References.- Miscellaneous Reactions.- Halogenation and De-Halogenation.- Addition to Carbon-Hetero Multiple Bonds.- Aromatic Substitution Reactions.- Cycloadditions.- Isomerisation and Rearrangements.- Addition to Carbon-Carbon Multiple Bonds.- Concluding Remarks.- References.- Index.- Abbreviations

Blurb

Metal Catalysed Reactions in Ionic Liquids

by Paul J. Dyson and Tilmann J. Geldbach

 

Metal Catalysed Reactions in Ionic Liquids is the first non-edited book on the subject of metal catalysed reactions in ionic liquids and covers the literature from its origins until early 2005.

The book begins with a general introduction to the field of biphasic/multiphasic catalysis and describes the synthesis, functionalisation and fundamental properties of ionic liquids relevant to catalysis. In the following chapters catalysed reactions are discussed according to their type, including:

hydrogenation

hydroformylation

oxidation

C-C coupling reactions

metathesis

dimerisation

polymerisation

 

Trends, generalisations, advantages and disadvantages of ionic liquids for specific reaction types are discussed. In addition, specific processes such as supported ionic liquid phase catalysis, continuous processes using CO₂ extraction and nanoparticle catalysis are covered.

This book is an invaluable resource for all those working in catalysis, green chemistry, and advanced synthetic methods, especially advanced level undergraduate and graduate students and those researching or contemplating research in biphasic or multiphasic catalysis using ionic liquids.