Magnetic Resonance in Colloid and Interface Science: Proceedings of a NATO Advanced Study Institute and the Second International Symposium Held at Men

ISBN-13: 9789400990814 / Angielski / Miękka / 2012 / 730 str.

J. Fraissard; H. a. Resing

Opis

In 1976, on the occasion of the Centennial of the Ameri can Chemical Society, H. A. RESrnG and C. G. WADE organized an international symposium on magnetic resonance in collo1d and in terface science which brought together a large number of scien tists from the United States and from abroad. The aim of this symposium was to include all experimental inorganic, organic and biochemical systems in which molecules are bound to interfaces and to show the contribution of various techniques based on ma gnetic resonance to the knowledge of these systems. This ambi tious program resulted into a very interesting gathering that initiated a more interdisciplinary approach to the problem of interfaces. Because of the success of this symposium it was sug gested that a similar meeting should be organized in Europe within the next three years. Professor J. FRAISSARD accepted this task but, conside ring the rapid developments in the theory and in the applica tions of the magnetic resonance spectroscopies, the organ1z1ng committee decided to arrange the meeting to be held in MENTON (France) in two parts, the first being a School and the second the Symposium proper. The former was' intended to review and to teach theoretical aspects as well as to discuss the experimental results derived from these advanced methods; the Symposium was to be for the discussion of the latest results at the highest level."

Spis treści

Lectures.- 1. Introduction Lecture to Magnetic Resonance.- 2. Electron Spin Resonance of Radicals and Ions in Solution.- 3. ESR Study of Powders g Factor, Transition Metal Ions, Various Symmetries.- 4. Hyperfine, Superhyperfine, Fine Structures.- 5. Application of EPR to Surface Chemistry: Coordination Chemistry of Paramagnetic Ions in Zeolites.- 6. Applications of EPR to Surface Chemistry: Study, Classification and Uses of Adsorbed Species.- 7. The Theory of Mossbauer Spectroscopy.- 8. Applications of Mossbauer Spectroscopy to Surface Chemistry.- 9. Magnetic Interactions of Nuclei with Electrons.- 10. NMR in Rigid Lattice: Application of Dipolar and Quadrupolar Interactions to the Study of Surface Properties and Adsorbed Phases.- 11. High Resolution Nuclear Magnetic Resonance of Solids.- 12. High Resolution NMR in Solids and Surfaces.- 13. NMR Techniques for Chemical Kinetics in Adsorption Systems.- 14. 13C Chemical Shifts in Adsorption Systems : Molecular Motions, Molecular Orientations, Qualitative and Quantitative Analysis.- 15. Nuclear Magnetic Resonance Study of Translational Motion in Porous Systems.- 16. NMR Chemical Shifts and Reactivity of Solid Surfaces.- 17. ESR and NMR Studies of Biological Interfaces. Membranes.- 18. Molecular and Ionic Behaviour at Water-Amphiphile Interfaces.- 19. Adsorption at Liquid/Liquid Interfaces: Discussion of NMR Methods.- 20. Behaviour of Macromolecules at the Solid Liquid Interface.- 21. Lipid-Protein Interactions in Biological Membranes. Spin-Label Studies.- 22. Applications of NMR to Micellar Interactions and Catalysis.- Papers.- 1. Mossbauer Spectroscopy Study of Iron with SO2-Polluted Atmospheres.- 2. A NGR Study of Iron Catalysts in CO Hydrocondensation Reactions.- 3. Proton NMR Powder Pattern Lineshapes and Single Crystal Rotation Studies of Hydrogen Molybdenum Bronzes.- 4. The NMR Response of Heterogeneous Systems: Anisotropy and Low-Dimensionality Effects.- 5. NMR and IR Study of the Protonated Species on the Surface of Scandia.- 6. The Proton NMR from Adsorbed H2 and Surface Hydroxyl Groups of Alumina and Molybdena-Alumina Catalysts.- 7. Application of the Nuclear Magnetic Resonance to the Study of the Superficial Constitutive Water of Titanium Oxides.- 8. Experimental Investigation and the Theoretical Treatment of the Surface Properties and Structure of CoO-MoO3-AI2O2 Catalysts.- 9. ENDOR Studies of Radicals Adsorbed on Metal Oxide Powders.- 10. Electron Transfer Across the Solid-Liquid Interface in Pigment Dispersions : Detection upon Photolysis by Spin Trapping.- 11. Influence of Preparation Methods on Structural Integrity of Na-A and Na-? Zeolites and on Occlusion of Aluminum Compounds Studied by H-NMR of Sorbed Water and Ammonia.- 12. EPR Investigation of Redox Processes Occurring upon Oxygen and Propylene Interaction with V2O5 and V2O5-MoO3.- 13. Sulfided Supported Tungsten and Molybdenum Catalysts Promoted by Nickel or Cobalt. An ESR Study.- 14. ESR Study of Polymerization on Al2O3 Fresh Surface Produced by Fracture.- 15. Electron Acceptor and Donor Properties of Oxides, as Investigated by Electron Spin Resonance Spectroscopy.- 16. ESR of Iron Impurity in NaPtY Zeolites.- 17. Computer Simulated Study of the EPR Spectrum of Cu2+ Hectorite.- 18. Photo-Adsorption of Oxygen on Al-Doped TiO2.- 19. Study by Magnetic Resonance Techniques (FMR, EPR, ENDOR) of the Reduction of NiII Ions in X-Type Zeolite.- 20. EPR Studies of Photochemistry at Molybdenum Oxide Surfaces.- 21. Incorporation du Platine dans l’Oxyde de Titane TiO2.- 22. An NMR and EPR Investigation of the Interaction of Chromium and Molybdenum Hexacarbonyl with Faujasite Type Y Zeolite.- 23. Carbon-13 NMR of Hydrocarbons Sorbed in Zeolites.- 24. An Electron Spin Resonance Investigation of a Molybdena/Alumina Catalyst and of Radical Cations Adsorbed on its Surface.- 25. EPR Study of Oxygen Intermediates and their Role in Mechanism of CO Oxidation on the Surface of Cr/SiO2 Catalysts.- 26. NMR Study of Adsorbed Water — III Molecular Orientation and Protonic Motions in the One-Layer of A Li Hectorite.- 27. EPR Study of the Potassium Palmitate — Water Lyotropic System.- 28. Diffusion Measurements of Small Molecules at the Gas Solid Interface.- 29. 19F NMR Spectroscopic and Relaxation Studies of SbF5 and AsF5 Intercalated in Graphite, Graphite Fibers and Polyacetylene.- 30. ESR of Colloidal Vanadium Pentoxide.- 31. ESR Analysis of Brownian Motion in V2O5 Xerogels after Adsorption of Water.- 32. A Study of Poly (Ethylene-Oxide) Chains Grafted on Silica by NMR.- 33. Carbon-13 NMR Investigation of Acetone Adsorbed on Silica Gel.- 34. Carbon-13 NMR Investigation of Surface Modified Silica Gels.- 35. Conformations of 1- and Trans 2-Butenes Adsorbed on a NaGeX Zeolite. A 13C-NMR Study.- 36. Nickel and Iron Carbonyl Decomposition on Zeolites and Alumina: Surface Complexes Detected by 13C-NMR Spectroscopy.- 37. Correlations Between the Motion and the Structure of Nonionic Surfactant Aggregates in Organic Solvents : Combined Studies by Carbon-13 Nuclear Magnetic Resonance and Neutron Scattering.- 38. Photoinitiated Electron Transfer Between Donors and Acceptors in Monomolecular Layer Assemblies — EPR and Optical Studies.- 39. Ion Binding in Amphiphile Water Systems. A Comparison Between Electrostatic Theories and NMR Experiments..- 40. Magnetic Resonance Studies of Graphite Lamellar Compounds.- 41. Molecular Dynamics in Water Solutions Adsorbed on Porous Solids Studied by ESR of Paramagnetic Probes.- 42. H-NMR Study on the Influence of Ion Exchange on Sorbate Mobility in Type A Zeolite.- 43. Nuclear Magnetic Resonance from Physisorbed Molecules at the Gas-Solid Interface.- 44. Phosphorus-31 and Sodium-23 NMR Studies of Diamagnetic Metal Ion Binding to Phosphatidylserine Vesticles.- 45. NMR Studies of Water in Barnacle Muscle Fibers.- 46. Magnetohydrodynamic Properties of an Amphiphilic Nematic Liquid Crystalline Mesophase.- 47. Etude de la Distribution de l—Alcool dans une Microemulsion par la Resonance Magnetique du Fluor.- 48. Solubilization in Aqueous Solutions of Hexadecyltrimethylammonium Bromide and Sodium Dodecylsulphate Studied by Nuclear Magnetic Relaxation.- 49. NMR of Aqueous Carrageenan Gels and Sols.- 50. Association Behavior in Steroidal Systems — NMR Spectroscopic and Vapor Pressure Osmometric Studies of Bile Acid Derivatives.