Iron-Carbene Complexes

ISBN-13: 9783540562580 / Angielski / Miękka / 1993 / 202 str.

Wolfgang Petz; J. Faust; J. Fa1/4ssel

Opis

This first volume in the series addresses graduate students in the fields of co-ordination compounds and organic synthesis. It covers the chemistry and structural aspects of iron-carbon compounds with an iron-carbon double bond.

Spis treści

1 Carbene Complexes with the 5LFe=C Moiety.- 1.1 Cationic Carbene Complexes with One Carbene Ligand Bonded to Fe.- 1.1.1 Cationic Complexes Containing the 5L(2D)2Fe=C or the 5L(2D-2D)Fe=C Moiety.- 1.1.1.1 Complexes of the Type [5L(2D-2D)Fe=CR2]+ with No Heteroatom at the Carbene Carbon Atom.- 1.1.1.2 Complexes [5L(2D)2Fe=C(R)ER]+ and [5L(2D-2D)-Fe=C(R)ER]+ with One Heteroatom at the Carbene Carbon Atom.- 1.1.2 Cationic Complexes Containing the 5L(CO)(2D)Fe=C Moiety.- 1.1.2.1 Complexes [5L(CO)(2D)Fe=CRR/]+with No Heteroatom at the Carbene Carbon Atom.- 1.1.2.2 Cations of the Type [5L(CO)(2D)Fe=C(R)ER’] + with One Heteroatom at the Carbene Carbon Atom.- 1.1.2.3 Cationic Carbene Complexes of the Type [5L(CO)(2D)Fe=C(ER)2]+ with Two Heteroatoms at the Carbene Carbon Atom.- 1.1.3 Cationic Complexes Containing the 5L(CO)2Fe=C Moiety.- 1.1.3.1 Cationic Complexes of the Type [5L(CO)2Fe =CRR’]+ without Heteroatom at the Carbene Carbon Atom.- 1.1.3.2 Cationic Complexes of the Type [5L(CO)2Fe=C(R) ER’]+ with One Heteroatom at the Carbene Carbon Atom.- 1.1.3.3 Cationic Complexes of the Type [5L(CO)2Fe =C(ER)2]+ with Two Heteroatoms at the Carbene Carbon Atom.- 1.1.4 Cationic Carbene Complexes with Additional Isocyanide Ligands.- 1.1.4.1 Complexes of the Type [5L(CO)(RNC)Fe=C(ER)2]+.- 1.1.4.2 Complexes of the Type [5L(RNC)2Fe=C(ER)2]+.- 1.2 Neutral Carbene Complexes.- 1.2.1 Carbene Complexes of the Type 5L(CO)(X)Fe=C(R)ER and 5L(CO)(X)Fe=C(ER)2.- 1.2.2 Carbene Compounds of the Type 5L(CO)(2D)Fe=C(R)ER and 5L(2D)2Fe=C(R)ER.- 1.2.3 Complexes of the Type 5L(CO)2Fe=C(ER)2.- 1.2.4 Complexes of the Type 5L(CO)RFe=C(ER)2.- 1.2.5 Neutral 19 Electron Carbene Complexes.- 1.3 Anionic Carbene Complexes.- 1.4 Carbene Compounds with Two Carbene Ligands.- 2 Vinylidene Complexes.- 2.1 Cationic Complexes of the Type [5L(2D-2D)Fe=C=CRR’]+ or [5L(2D)2Fe=C=CRR,]+.- 2.2 Cationic Complexes of the Type [5L(CO)(2D)Fe=C=CRR’]+.- 2.3 Cationic Complexes of the Type [5L(CO)2Fe=C=CRR’]+.- 2.4 Cationic Compounds of the Type [Cp(CO)(2D)FeC(2D’)=CRR’]X, [Cp(CO)Fe(?-2D-2D’)C=CRR’]X, and [Cp(CO)2FeC(2D)=CRR’]X.