Intro Free Radical Chemistry

ISBN-13: 9780632052929 / Angielski / Miękka / 2000 / 252 str.

Andrew W. Parsons; A. F. Parsons; T. Parsons

Opis

The past twenty years has seen an explosion of interest in free radicals, as their pivotal role in both chemistry and biology has come to light. This introductory textbook aims to capture this excitement for advanced level undergraduates, with particular emphasis on the importance of radical reactions in organic synthesis. The book provides a gentle, stepwise introduction to the subject, taking the student from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes, allowing the relevance of the subject to be grasped more easily. Suitable for advanced level undergraduates and postgraduates in chemistry and biochemistry, the book will also be invaluable for research level scientists requiring an update in the area.

Spis treści

Chemical Abbreviations.

Preface.

1. Radicals and their Importance.

2. The basics.

3. Radical Initiation.

4. Radical Reactions.

5. Radicals in Synthesis.

6. Foundational Group Transformations.

7. Intramolecular Cyclization Reactions.

8. Intermolecular Reactions.

9. Radical Translocation Reactions.

10. Radical Anions.

11. Radical Cations.

Questions.

Outline Answers.

Further Reading.

Index.

O autorze

Dr Andrew F. Parsons is a senior lecturer in the Department of Chemistry, University of York, UK.

Blurb

The past twenty years have seen an explosion of interest in free radicals as their pivotal role in both chemistry and biology has come to light. From their beneficial role in the manufacture of plastics to their detrimental effects on the Earth s ozone layer, radical reactions impact significantly on our daily lives.

An introduction to Free Radical Chemistry provides a concise introduction to free radical chemistry from an organic chemistry perspective, highlighting the importance of radical, radical anion and radical cation reactions in synthesis. The book provides a step–wise introduction to the subject, taking the student from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes. With case studies to illustrate reactions in landmark syntheses and problems (with outline answers) to test the reader s understanding, this textbook is suitable for advanced level undergraduates and postgraduates in chemistry and biochemistry. It will also be invaluable for research level scientists requiring and update in the area.