Inorganic Syntheses, Volume 34

ISBN-13: 9780471647508 / Angielski / Twarda / 2004 / 288 str.

John R. Shapley;Inorganic Syntheses Inc; Inc Inorganic Syntheses

Opis

This series provides inorganic chemists with detailed and foolproof procedures for the preparation of important and timely compounds. Volume 34 continues to report such procedures with an up-to-date selection of contributions by internationally-recognized researchers, including the following:

Recenzje

will not only serve as a resource for reliable synthetic procedures, but also attract and potentially inspire even a cursory reader ( Applied Organometallic Chemistry, Vol.19, No.1, January 2005)

Spis treści

Chapter One MAIN GROUP COMPOUNDS.

1. Diborane(4) Compounds.

2. Sodium Tetrakis(3,5–bis(trifluoromethyl)phenyl)borate, Na[B(3,5–(CF₃)₂C₆H₃)₄].

3. Anionic Tris– and Bis(diphenylphosphinomethyl)borates.

4. Six–Coordinate Aluminum Cations Based on Salen Ligands.

5. Tabular –Alumina.

6. Para–Substituted Aryl Isocyanides.

7. Unsymmetric Tripod Ligands Related to Tris(pyrazol–1–yl)methane.

8. Difluorotriphenylarsenic(V), AsF₂Ph₃.

9. Tetramethylammonium Salts of Superoxide and Peroxynitrite.

10. Tellurium Nitrogen Compounds.

Chapter Two ORGANOMETALLIC AND COORDINATION COMPLEXES.

11. Addition Compounds of Dibromodioxomolybdenum(VI).

12. Oxorhenium(V) Oxazoline Complexes for Oxygen Atom Transfer.

13. Allyl and Dienyl Complexes of Ruthenium.

14. Tris(4,7–diphenyl–1,10–phenanthroline)ruthenium(II) Chloride, [Ru(4,7–Ph₂phen)₃]Cl₂.

15. Metal Complexes of a Diimino(tetracyano)pyrrolizinide Ligand Derived from Tetracyanoethylene.

16. Cationic Pt(II) Complexes of Tridentate Amine Ligands.

17. Platinum(II) Complexes of Propanone Oxime.

18. Trifluoromethanesulfonatosilver(I) Derivatives.

19. Pentakis(tetrahydrofuran)dicadmium Tetrakis(tetrafluoroborate), [Cd₂(THF)₅][BF₄]₄.

20. Di(µ–chloro)bis{chlorodioxobis(tetrahydrofuran)uranium(VI)}, {UO₂Cl₂(THF)₂}₂.

Chapter Three TRANSITION METAL CARBONYL COMPOUNDS.

21. Hexacarbonylvanadate(1–) and Hexacarbonylvanadium(0).

22. Tricarbonyltris(pyridine)molybdenum(0) and Its Use as a Mo(0) Source for Allylmolybdenum(II) Complexes.

23. A Tungsten(0) Fullerene–60 Derivative.

24. Dodecacarbonyltriruthenium, Ru₃(CO)₁₂.

25. Dicarbonylbis(hexafluoroacetylacetonato)ruthenium, Ru(CO)₂(hfac)₂.

26. Carbonyl Complexes of Ruthenium(II) from Dimethylformamide.

27. Rhodium(I) and Iridium(I) Carbonyl Complexes.

28. Useful Mononuclear Rhodium(I) and Iridium(I) Compounds.

Chapter Four CYANIDE COMPOUNDS.

29. Hexacyanometallates as Templates for Discrete Pentanuclear and Heptanuclear Bimetallic Clusters.

30. A Mixed–Valence Heptanuclear Iron Complex.

31. Potassium Hexacyanochromate(III) and Its ¹³C–Enriched Analog.

32. Two Polynuclear Nickel(II) Hexacyanochromate(III) Complexes.

33. Trimethyltriazacyclononanechromium(III) Complexes and a Chromium(III)–Nickel(II)–Cyanide Cluster with a Face–Centered Cubic Geometry.

34. Cyano–Bridged M(II)₉M(V)₆ Molecular Clusters, M(II) = Mn,Co,Ni; M(V) = Mo,W.

35. Cyanometal–Substituted Derivatives of the Fe₄S₄ Cluster Core.

36. Tricyanometalate Building Blocks and Organometallic Cyanide Cages.

37. Phosphine Ligand Derivatives of Diamond–Shaped, Cyanide–Bridged Iron(II)–Copper(I) Complexes.

38. Cyanide–Bridged Iron(II)–M(II) Molecular Squares, M(II) = Fe(II), Co(II),Cu(II).

39. Poly{(2,2′–(bipyridine)(triphenylphosphine)bis(dicyanocopper(I)}, {(CuCN)₂(bpy)(PPh₃)}_n.

Chapter Five CLUSTER AND POLYNUCLEAR COMPOUNDS.

40. A Tetranuclear Lanthanide–Hydroxo Complex Featuring the Cubane–like [Ln₄(µ₃–OH)₄]⁸⁺ Cluster Core, [Nd₄(µ₃–OH)₄(H₂O)₁₀ (alanine)₆] [ClO₄]₈.

41. Tetradecachlorohexatantalum Octahydrate, Ta₆Cl₁₈.8H₂O.

42. Polyoxomolybdate Clusters: Giant Wheels and Balls.

43. Tetrakis{n⁶–1–isopropyl–4–methylbenzene)ruthenium(II) tetraoxomolybdate(VI)}.

44. Diruthenapenta– and Diruthenahexaboranes.

45. Mixed–Metal Clusters of Iridium with Ruthenium and Osmium.

46. Tri– and Hexaruthenium Carbonyl Clusters.

47. Silica–Mediated Synthesis of Os₃(CO)10(µ–H)(µ–OH).

48. Efficient Base– and Silica–Mediated Syntheses of Osmium Cluster Anions from –{Os(CO)₃Cl₂}₂.

49. Triosmium Complexes of Fullerene–60.

50. Triphenylphosphine–Stabilized Gold Nanoparticles.

Contributor Index.

Subject Index.

Formula Index.