Inorganic Syntheses, Volume 32

ISBN-13: 9780471249214 / Angielski / Twarda / 1998 / 368 str.

Marcetta Y. Darensbourg;Darensbourg

Opis

The Inorganic Synthesis Series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. This new volume includes information on water-solubilizing ligands for organometallics, labile ligand complexes, and the syntheses of cluster compounds and hydrides.

Spis treści

Chapter One LIGANDS FOR WATER–SOLUBILIZING ORGANOMETALLIC COMPOUNDS.

1. (Meta–Sulfonatophenyl)Diphenylphosphine, Sodium Salt and Its Complexes with Rhodium(I), Ruthenium(II), Iridium(1).

2. Syntheses of Water–Soluble Phosphines and Their Transition Metal Complexes.

3. Tris[Tris(Sodium m–sulfonatophenyl)phosphino] Palladium(0)–Enneahydrate.

4. Sulfonated Phosphines.

5. (S,S)–2,3–Bis[Di(m–Sodiumsulfonatophenyl)phosphino]butane–(chiraphos_TS) and (S,S)–2,4–Bis[di(m–Sodiumsulfonatophenyl)–phosphinolpentane (BDPP_TS).

6. 1,3,5–Triaza–7–phosphatricyclo[3.3.1.1^3,7]decane and Derivatives.

Chapter Two BIOMIMETIC AND SPECIAL PROPERTY LIGANDS.

7. 2.2′:6′,2"–Terpyridine.

8. Poly(1–pyrazolyl)alkane Ligands.

9 . Tris[N–(3–tert–butyl)pyrazolyl]methane.

10. Tris[2–(1,4–Diisopropylimidazolyl)]phosphine.

11. Tris[(2–pyridyl)methyl]amine (TPA) and (+)–Bis[(2–pyridyl)–methyl]–l–(2–pyridyl)ethylamine (a–MeTPA).

12. C₂–Symmetric 1,4–Diisopropyl–7–R–l,4,7–Triazacyclononanes.

13. N–(2–hydroxyethyl)–3,5–Dimethylpyrazole, a Dinuclear Copper Complex, and N–(2–p–Toluenesulfonylethyl)–3,5–dimethy–pyrazole.

14. N–(2–Mercaptoethyl)–3,5–dimethylpyrazole.

15. 1,5–Diazacyclooctane, Pendant Arm Thiolato Derivatives and [N,N′–Bis(2–Mercaptoethyl)–1,5–Diazacyclooctanato]–nickel(II).

16. Polydentate Thiolate and Selenolate Ligands, RN(CH₂,CH₂,S(Se)^–)₂, and Their Dimeric and Mononuclear Ni(II) Complexes.

17. Poly[(methylthio)methyl]borates and Representative Metal Derivative.

18. Polyaza Binucleating Ligands: OBISTREN and OBISDIEN.

19. N,N′.bis(2–hydroxybyl.thylenediamine–N,N′–diacetic acid (HBED).

20. N–Tert–Alkyl–Anilides as Bulky Ancillary Ligands.

21. 1,2–Bis(Dichlorophosphino)–1,2–Dimethylhydrazine and Alkoxy/Aryloxy Derivatives.

22. Tris[(tert–butylamino)–dimethylsilyl]methylsilane and Its Precursors.

Chapter Three TRANSITION METAL COMPLEXES AND PRECURSORS.

23. Facile Synthesis of Isomerically Pure.

24. cis–Bis(benzeneacetonitrile)dichloroplatinum(II) and trans–Bis(benzeneacetonitrile)dichloroplatinum(II).

25. Platinum(II) Complexes of Dimethyl Sulfide.

26. (2,2′ :6′,2"–Terpyridine) Methylplatinurn(II) Chloride and (l,l0–Phenanthroline)methylchloroplatinum(II).

27. (N,N–Chelate)(olefin)platinum(0) Complexes.

28. Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes.

29. 2,4–Pentanedionatogold(I) Complexes and 2,4–Pentanedionatothallium.

30. Tetrakis(Pyridine)SiIver(2 + )Peroxydisulfate.

31. One–Pot Synthesis of Tetrahydronium Tris(4,4′–Dicarboxylato–2,2′–Bipyridine)ruthenium(II) Dihydrate.

32. Trichloro[2,2′ :6,2"–Terpyridine]ruthenium(III) and Phosphine Ligand Derivatives.

33. Monomeric Tetrahydrofuran–Stabilized Molybdenum(III) Halides.

34. Facial Molybdenum(lI1) Triamine Complexes.

35. High–Valent Mono–(5–Pentamethylcyclopentadienyl)vanadium and Molybdenum Complexes.

36. Monoindenyltrichloride Complexes of Titanium(IV), Zirconium(IV), and Hafnium(IV).

37. Labile Copper(I) Chloride Complexes: Preparation and Handling.

Chapter Four MAIN GROUP AND TRANSITION METAL CLUSTER COMPOUNDS.

38. 7,8–Dicarbaundecaborane(13).

39. Borazine, Polyborazylene, B–Vinylborazine and Poly(B–Vinylborazine).

40. Transition Metal Complexes of the Lacunary Heteropolytungstate, [P₂W₁₇O₆₁] ^10–.

41. Bis(Triphenylphosphorany1idene)A mmonium µ–Carbonyl–1kC:2kC–Decacarbonyl–1k³C,2k³,3k⁴C–µ–Hydrido–1k:2k–triangubTriruthenate(1 ).

42. Dipotassium Undecacarbonyl Trimetallate(2 ) Clusters, K₂[M₃(CO)₁₁] (M = Ru, Os).

43. [PPN]₂[Ru₃(CO)₁₁] and [PPN]₂[OS₃(CO)₁₁], µ–Nitrido–Bis(Triphenylphosphorus) (1 +) Undecacarbonyltriruthenate (2  ) and Undecacarbonyltriosmate(2  ).

44. Platinum–Ruthenium Carbonyl Cluster Complexes.

45. Tri(µ–carbonyl)nonacarbonyltetrarhodiu.

46. High Nuclearity Hydridodecaruthenium Clusters.

Chapter Five MAIN GROUP AND TRANSITION METAL HYDRLDES.

47. Dichlorodihydro(N,N,N′,N,–Tetraethyl–1,2–ethanediamine–N,N′)silicon.

48. Tricarbonyl(hydrido)[1,2–bis(diphenylphosphino)ethane]–manganese as Precursor to Labile Site Derivatives.

49. Pentahydridobis(tricyclohexylphosphine)iridium(V) and trihydridotris (triphenylphosphine)iridium(III).

Chapter Six TITANIUM(1II) CHLORIDE.

(A Correction to Inorganic Syntheses, Vol. 24, pp. 181 (1986).

50. An Active Form of Titanium(II1) Chloride.

Contributor Index.

Subject Index.

Formula Index.

Chemical Abstracts Service Registry Number Index.