Higher Oxidation State Organopalladium and Platinum Chemistry

ISBN-13: 9783642174285 / Angielski / Twarda / 2011 / 186 str.

Allan J. Canty

Opis

This volume covers the role of higher oxidation state species in platinum-mediated C-H bond activation and functionalization, carbon-heteroatom bond-forming reductive elimination from palladium (IV) complexes, and much more.

Recenzje

From the reviews:

"This is a nice up to date book that provides a very readable account of highlights in a topical and exciting area of developing chemistry. All the contributors and the editor ... are to be congratulated for making available such a well produced and interesting monograph. ... This monograph will be of value to all those who are working in the area, and it should be in libraries wishing to keep up to date in these chemical areas that have so much potential." (Martyn V. Twigg, Platinum Metals Reviews, Vol. 56 (2), 2012)

Spis treści

Five-Coordinate Platinum(IV) Complexes.- The Role of Higher Oxidation State Species in Platinum-Mediated C-H Bond Activation and Functionalization.- Carbon-Heteroatom Bond-Forming Reductive Elimination from Palladium(IV) Complexes.- Palladium(IV) Complexes as Intermediates in Catalytic and Stoichiometric Cascade Sequences Providing Complex Carbocycles and Heterocycles.- h¹-Alkynyl Chemistry for the Higher Oxidation States of Palladium and Platinum.- Palladium(III) in Synthesis and Catalysis.- Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d¹⁰ and s² Centers.

Blurb

Kyle A. Grice, Margaret L. Scheuermann and Karen I. Goldberg: Five-Coordinate Platinum(IV) Complexes.- Jay A. Labinger and John E. Bercaw: The Role of Higher Oxidation State Species in Platinum-Mediated C-H Bond Activation and Functionalization.- Joy M. Racowski and Melanie S. Sanford: Carbon-Heteroatom Bond-Forming Reductive Elimination from Palladium(IV) Complexes.- Helena C. Malinakova: Palladium(IV) Complexes as Intermediates in Catalytic and Stoichiometric Cascade Sequences Providing Complex Carbocycles and Heterocycles.- Allan J. Canty and Manab Sharma: h¹-Alkynyl Chemistry for the Higher Oxidation States of Palladium and Platinum.- David C. Powers and Tobias Ritter: Palladium(III) in Synthesis and Catalysis.- Marc-Etienne Moret: Organometallic Platinum(II) and Palladium(II) Complexes as Donor Ligands for Lewis-Acidic d¹⁰ and s² Centers.