High-Temperature Polymer Nanocomposites Based on Heterocyclic Networks from Nitrile Monomers

ISBN-13: 9783031329425 / Angielski

Vladimir A. Bershtein;Pavel N. Yakushev

Opis

This book presents an overview of polymer nanocomposites for use in various high-temperature applications. Specifically, it focuses on the structure and physical properties of nanocomposites based on heterocyclic matrices derived from nitrile monomers such as cyanate esters or phthalonitriles. Due to increasing interest in new heat-resistant, lightweight materials for use in extreme conditions, such as in aeronautics, microelectronics, and various industrial machinery, the high thermal stability of heterocyclic polymer networks, in particular, has attracted much attention from materials researchers and engineers. Featuring a comprehensive review of the most recent advances in research on the structure and physical properties of these promising high-temperature polymer nanocomposites, this book will be of particular interest to materials scientists and engineers working throughout the fields of aeronautical and microelectronic engineering. In general, this book is intended for use by researchers of composite materials and specialists engaged in material selection for work in extreme conditions; for students specializing in materials science; for polymer physicists, and for university libraries.

Spis treści

Preface

Abbreviations

Part I.  Recent Advances in Studying Cyanate Ester Resin-based  

              Nanocomposites

    Chapter 1.  CER/POSS nanocomposites                                           

             1.1  Structure of the nanocomposites derived from dicyanate ester of bisphenol E                                       

                      (DCBE) monomer and PT-30 oligomer

             1.2   Properties of DCBE- and PT-30- based CER/POSS nanocomposites

             1.3   Influence of varying chemical structure of CER matriх on the properties

                      of POSS containing nanocomposites

   Chapter 2.   CER/Montmorillonite (MMT) nanocomposites

             2.1   Structure and molecular dynamics of nanocomposites

             2.2  The impact  of functionalized MMT nanolayers on the properties of nanocomposites

   Chapter 3.   Nano- and subnanocomposites with silica units introduced by a sol-gel method

             3.1  Nanostructure

             3.2  Molecular dynamics and properties

             3.3. The nature of the exceptional impact of ultra-low silica contents on the properties of  

                       CER-based subnano- and nanocomposites

   Chapter 4. Other nanocomposites.        

             4.1   Nanocomposites with silica particles

             4.5   Nanocomposites with carbon nanofillers

     References

Part II. Recent Advances in Studying Phthalonitrile Nanocomposites                    

   Chapter 5.  Phthalonitrile composites with POSS nanoparticles

              5.1. Synthesis and spectroscopic control of molecular structure and mobility

              5.2  Nanostructure

              5.3  Glass transition and dynamic mechanical behavior

              5.4  Other properties

   Chapter 6.  Phthalonitrile /Montmorillonite nanocomposites:

              6.1   Structure

              6.2   Моlecular dynamics and properties

    Chapter 7. Phthalonitrile /metal oxide nanocomposites

               7.1   Phthalonitrile /Titania and ZnO nanocomposites

               7.2   Phthalonitrile /Alumina nanocomposites

    Chapter 8. Other 

O autorze

Prof. Dr. Sci. Vladimir A. Bershtein

Vladimir A. Bershtein, born in Leningrad (St.-Petersburg, Russia), was graduated Master’s degree on polymers technology from Leningrad Technological Institute in 1954. He completed his PhD degree in  1963 and Dr. Sci. (Phys.-Math.) dissertation in 1980. He is Professor from 1991. From 1965 up to now he is  Leading Research Scientist and Head of research group in Materials Dynamics Laboratory, Department of Solid State Physics, at the Ioffe Institute of the Russian Academy of Sciences, St.-Petersburg, Russia.

Dr. Pavel N. Yakushev

Pavel N. Yakushev, born in Leningrad, Russia, graduated Master’s degree on Electronics from named at present Peter the Great St.-Petersburg Polytechnic University in 1977, and then joined to  the Solid State Physics Department of the Ioffe Institute of the Russian Academy of Sciences, where he completed his PhD in 1988 and now is a Senior researcher. Having worked at several  laboratories abroad within the framework of international exchange programs, he e.g. spent a half an year at  the  Ford Research Laboratories,  Dearborn,  USA. Currently, he is investigating the anomalies of segmental dynamics, nanoscale dynamic/structural/compositional heterogeneity, and  nanostructure-dynamics-properties relationships in complex polymer systems and nanocomposites.