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Heterogeneous Ferroelectric Solid Solutions: Phases and Domain States
ISBN-13: 9783030092535 / Angielski / Miękka / 2018 / 192 str.
Heterogeneous Ferroelectric Solid Solutions: Phases and Domain States
ISBN-13: 9783030092535 / Angielski / Miękka / 2018 / 192 str.
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As the first book on phases and domain states in ferroelectric solid solutions, this volume goes beyond its basic treatment of the subject to offer practical applications, dealing with perovskite-type ferroelectric solid solutions for modern materials science.
1 Crystallographic Aspects of Interfaces in Ferroelectrics and Related
Materials...........................................................................................................................
1.1 Domain Structures and Interfaces Between Polydomain Regions...............
1.1.1 Formation of Domain Structures in Ferroelectric Single
Crystals &n
bsp; .........1.1.2 Elastic-matching Concept and Its Application to Domain Boundaries
1.1.3 Classification of Domain Boundaries in Ferroelectric Single Crystals &nbs
p;1.1.4 Crystallographic Interpretation of Interfaces Between Complicated
Domain Structures.....................................................................................
1.2 Phase Coexistence at First-order Phase Transitions.........................................
1.2.1 Elastic Matching of Phases and Zero-net-strain Planes......................
1.2.2 Stress Relief and Conical Interphase Boundaies.................................
1.2.3 Three-Phase States........................................................................
1.3 Polydomain / Heterophase Ferroelectrics ......................................................... .......
1.4 References ..............................................................................................................
2 Two-Phase States.............................................................................................................
2.1&nbs
p; Elastic Matching of Morphotropic Phases in Pb(Zr1–xTix)O3........................... 2.1.1 Tetragonal-rhombohedral Phase Coexistence and
Crystallographic Interpretation...............................................................
2.1.2 Elastic Matching and Stress Relief in the Presence of the Intermediate Monoclinic Phase
2.2 Phase Coexistence in (1 – x)Pb(Mg1/3Nb2/3)O3 – xPbTiO3 Near the Morphotropic Phase Boundary
2.2.1 Phase Coexistence Without the Monoclinic Phase..............................
2.2.2 Phase Coexistence in the Presence of the Intermediate Monoclinic Phases
2.2.3 Effect of Non-180° Domains on Phase Coexistence..........................
2.2.4 Different Scenarios of Stress Relief........................................................
2.3
; Model of Interpenetrating Phases: Application to(1 – x)Pb(Mg1/3Nb2/3)O3 – xPbTiO3 Near the Morphotropic Phase Boundary...................................................................................................
2.4 Domain and Heterophase States in (1 – x)Pb(Zn1/3Nb2/3)O3 – xPbTiO3 Near the Morphotropic Phase Boundary
2.4.1 Phase Transitions and Intermediate Phases.........................................
; 2.4.2 Crystallographic Study of Elastic Matching of Morphotropic Phases ...................................................................................
2.4.3 Interpenetrating Phases in 0.90Pb(Zn1/3Nb2/3)O3 – 0.10PbTiO3 Single Crystals.............................................................................................
2.5 Specifics of Two-Phase States in Ferroelectric Solid Solutions ......... ……
2.6 References........................................................................................................................
3 Phase Coexistence Under Electric Field ...................................................................
3.1 Heterophase Pb(Mg1/3Nb2/3)O3 at the Induced Phase Transition..............3.2 Domain State – Interface Relationships at Electric Field E || [001]........
3.2.1 Heterophase (1 – x)Pb(Mg1/3Nb2/3)O3 – xPbTiO3...................................
3.2.1.1 Phase Sequences and Diagrams at x ³ 0.30.........................
3.2.1.2 &
nbsp; Phase Sequences and Diagrams at x £ 0.28.........................3.2.2 Heterophase (1 – x)Pb(Zn1/3Nb2/3)O3 – xPbTiO3....................................
3.2.2.1 Elastic Matching of Phases at x = 0.08–0.09.......................3.2.2.2 Diagrams at x = 0.045...............................................................
3.3 Domain State – Interf
ace Relationships at Electric Field E || [110]..............3.4 Domain State – Interface Relationships at Electric Field E || [111].
3.5 Role of Intermediate Phases in Heterophase States .......................................
3.6 References...............................................................................................................4 Three-phase States..........................................................................................................
4.1 Model of Three-phase Single Crystal..................................................................
4.2
; Application of Model Concepts to PbZrO3 and Pb(Zr1–xTix)O3(x » 0.22).................................................................................................
4.2.1 Phase coexistence in PbZrO3 Single Crystals..........................................
4.2.2 Phase coexistence in Pb(Zr1–xTix)O3 Single Crystals..............................
4.3 Application of Model Concepts to (1 – x)Pb(Mg1/3Nb2/3)O3 –
&nbs
p; xPbTiO3)..................................................................................................4.4 Three-phase Coexistence and Complete Stress Relief in
(1 – x)Pb(Zn1/3Nb2/3)O3 – xPbTiO3.........................................................
4.5 Thermodynamic Description of Three-phase States in Ferroelectric
Solid Solutions........................................................................................
4.6 Crystallographic and Thermodynamic Studies of Three-phase States...........
............................................................................................4.7 References...............................................................................................................
5 Overlapping Structures and Transition Regions....................................................
5.1 Overlapping Structures in Pb(Zn1/3Nb2/3)O3............................................
5.2 Domain State – Interface Relationships in Pb(Zn1/3Nb2/3)O3..........................
5.3 Transition Regions in (1 – x)Pb(Zn1/3Nb2/3)O3 –
xPbTiO3.................................5.4 Stress Relief at Variable Unit-cell Parameters...................................................
5.5 References...............................................................................................................
6 Relations Between Domain States and Heterophase Structures in
Lead-free Ferroelectric Solid Solutions....................................................................
6.1 Phase Coexistence in (1 – x)(Na1/2Bi1/2)TiO3 – xBaTiO3 ..................... <
6.1.1 Domain States and Elastic Matching of Phases........
..................................6.1.2 Phase Contents near the Morphotropic Phase Boundary............................
6.1.3 Anisotropy of Unit-cell Distortions and Heterophase Structures..............
6.2 Phase Coexistence in Ba(Ti1-xCex)TiO3..................................................6.2.1 Relations Between Domain and Heterophase States Near the Morphotropic
Phase Boundary..................................................................................................... <
6.2.2 Phase Contents and Stress-relief Conditions......
...............................................6.3 Features of Heterophase States in Ba(Ti1−xZrx)O3 and Related Solid
Solutions...................................................................................................................
6.4 Domain States and Phase Contents in Ba(Ti1-xSnx)O3 and
Ba(Ti1-xHfx)O3 near the Morphotropic Phase Boundary............................
6.5 Behaviour of Unit-cell Parameters and Heterophase Structures..................
6.6 References............................................
...................................................................7 Conclusions.......................................................................................................................
7.1 A Way from a Unit Cell to Morphotropic Polydomain /
Heterophase Structures.........................................................................................
7.2 References...............................................................................................................
Appendix A. Methods for Description of Heterophase and Polydomain Single Crystals
A.1 Concepts on the Zero-net-strain Plane...............................................................A.2
; Comparison of Data..............................................................................................A.3 References............................................................................................................... .......
Appendix B. Optimal Volume Fractions in Terms of AnglesBetween Spontaneous Polarization Vectors Near the Morphotropic
Phase Boundary..............................................................................................................
B.1 Optimal Volume Fractions and Polarization Rotations..................................
B.2 References...............................................................................................................
List of Abbrevi
ations..................................................................................................... About the AuthorVitaly Yuryevich Topolov received the the degrees “Candidate of Sciences (Physics and Mathematics)” and “Doctor of Sciences (Physics and Mathematics)” in 1987 and 2000, respectively from the Rostov State University, Russia. From 1987 to 1991, he worked as a Research Scientist of the Institute of Physics at the Rostov State University, from 1991 to 2000 as a Senior Lecturer (1991–1992) and an Associate Professor (1992–2000) of the Department of Physics at the Rostov State University. In 2000, he became an associate professor at the same Department. In 2011 he was appointed full professor of the Department of Physics and High Technologies at the Southern Federal University. He has been a Corresponding Member of the Russian Academy of Natural Science (Moscow, Russia9 since 2010).
He was also a visiting scientist at the Moscow State University, Russia (former USSR, 1989), University of Saarland, Germany (1994–1995), Aachen University of Technology – RWTH Aachen, Germany (1998), Karlsruhe Research Center, Germany (2002 and 2003–2004), University of Bath, UK (2006, 2007, 2012, 2013, and 2014), and University of Roma “Tor Vergata”, Italy (2008). His research interests include heterogeneous ferroelectrics, smart materials, domain and heterophase structures, as well as electromechanical effects in ferroelectrics and related materials. He earned the special award from the International Science Foundation (1993) and the Soros and awards from the International Soros Science-Educational Program and the Open Society Institute in 1997, 1998, 2000, and 2001.He authored three monographs published by Springer, various chapters in books published by Nova Science Publishers (New York, USA),and about 370 scientific papers.
Christopher Rhys Bowen earned a BSc in Materials Science at the School of Materials, University of Bath, UK in 1990 and worked on his DPhil thesis in ceramics in the Department of Materials, University of Oxford, UK in 1990–1993 (PhD awarded in 1994). In 1993–1994, he worked as a Researcher in the Advanced Ceramics Group at the Technical University of Hamburg-Harburg (TUHH). From 1994 to 1996, he was research fellow at the School of Materials, University of Leeds, UK. From 1996 to 1998, he was a Senior Scientist at DERA, Functional Materials Group, UK. He joined the University of Bath in August 1998 and is now a Professor at the same University.
The research interests of Prof. C. R. Bowen are concerned with functional ceramics, including ferroelectric ceramics and composites for modern sensors and actuators, as well as with manufacturing and characterisation of these materials. He earned the Thornton and Hazelwood prizes for academic work (1986–1990), Institute of Materials National Lecture Competition award (1993), SET award (2002), and John Willis award for excellence in research and teaching (2003). He is the author two monographs published at Springer and chapters in monographs published at Nova Science. He has published approximately 200 scientific papers. He is currently supported by the European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013) / ERC Grant Agreement no. 320963 on Novel Energy Materials, Engineering Science and Integrated Systems (NEMESIS).This book systematizes data on the heterophase states and their evolution in perovskite-type ferroelectric solid solutions. It also provides a general interpretation of heterophase and domain structures on changing temperature, composition or electric field, as well as the complete analysis of interconnections domain structures, unit-cell parameters changes, heterophase structures and stress relief. The description of numerous examples of heterophase states in lead-free ferroelectric solid solutions is also included. Domain state–interface diagrams put forward the interpretation of heterophase states in perovskite-type ferroelectric (FE) solid solutions and describe the stress relief in the presence of polydomain phases, the behavior of unit-cell parameters of coexisting phases, the effect of external electric field etc. This 2nd edition generalizes the results on the heterophase ferroelectric solid solutions and the stress relief and presents new results on heterophase/domain structures and phase contents in lead-free ferroelectric solid solutions.
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