Handbook of Phase Transfer Catalysis

ISBN-13: 9780751402582 / Angielski / Twarda / 1997 / 564 str.

Yoel Sasson;Neumann;Sasson

Opis

Phase transfer catalysis is a sophisticated chemical technique which can be used to perform a variety of chemical reactions under mild conditions and with improved control. Since the concept was developed, both the theoretical and practical synthetic applications have seen considerable development, to the point where the technique can be applied to many areas of chemistry. Thus, phase transfer methods are now utilized in many applications, from research chemistry to full-scale production, where the benefits of faster, cleaner and more selective reactions are required.
In this new book, the editors have brought together a range of contributors, each of whom is working at the forefront of the technology, to provide a clear, concise and ahtoritative review of this important area of chemistry.
Industrial and academic chemists working on the synthesis, scale-up, production or analysis of a wide range of chemical products will find this book an essential reference on phase transfer technology.

Spis treści

Nucleophilic aliphatic and aromatic substitutions in phase transfer catalysis; mechanism and synthetic applications. Kinetics and modelling of catalytic phase transfer systems. Synthesis of quaternary ammonium salts. Phase transfer catalysed reactions under basic conditions. Applications of phase transfer catalysis in the chemical industry. PTC in polymer synthesis. PTC in carbohydrate chemistry. PTC in heterocyclic chemistry. Phase transfer catalysis in oxidation processes. Organometallic reactions under phase-transfer conditions. Sonochemical and microwave activation in phase transfer catalysis. Analytical applications of phase transfer catalysis. Triphase catalysis. Chiral phase transfer catalysis. Chemical modification of polymers via phase transfer catalysis. Phase transfer catalysis of uncharged species.