Handbook of Bond Dissociation Energies in Organic Compounds

ISBN-13: 9780849315893 / Angielski / Twarda / 2002 / 392 str.

Yu-Ran Luo; Robert J. Ahrens; Thomas J. Rice

Opis

With data on over 2900 bonds in 2500 organic compounds, the Handbook of Bond Dissociation Energies in Organic Compounds is the first comprehensive collection of experimental BDE data and is sure to be welcomed by chemists around the world. It is organized by bond type within 49 separate tables, and for each bond type, the data are classified by functional group, bond order, bond degree, and molecular size and structure. The author presents up to five experimental values for each dissociation, highlights the recommended value, and lists with each the experimental method used and references. An outstanding format and complete indexing both by compound name and by chemical formula make searching for data quick and easy. Presents the first comprehensive collection of reliable experimental BDE data for organic compounds Offers up to five BDE values for each compound, highlights the recommended value, and provides references for each Organizes data by bond type, functional group, bond order, bond degree, and molecular size and structure Includes a chapter that provides analyzed heats of formation Includes a chapter containing BDE data for some inorganic compounds

Recenzje

"Readers who use the NIST-JANAF Thermochemical Table, the NIST web site, or the many other derived thermochemical resources will find this handbook to be a very convenient, easy-to-read … resource. Readers will be able to quickly determine the most accurate experimentally measured BDE that can be compared to derived values."
- IEEE Electrical Insulation, Sept/Oct 2004, Vol. 20, No. 5

Spis treści

INTRODUCTION
A Database of the BDEs
What is the BDE?
Why We Need Reliable BDEs
Scope of this Book
On Energy Units
How to Search for BDEs in this Book
How to Use the Tables of the BDE Data
EXPERIMENTAL METHODS FOR MEASURING BDEs
TABULATED BDES OF C-H BONDS
Chain-Saturated Hydrocarbons
Chain-Unsaturated Hydrocarbons
Cyclic Hydrocarbons
Aromatic Hydrocarbons
Halogenated Hydrocarbons
Organic Compounds Containing Heteroatoms
TABULATED BDES OF C-C BONDS
Saturated Hydrocarbons
Chain-Unsaturated Hydrocarbons
Aromatic Hydrocarbons
Halogenated Hydrocarbons
Organic Compounds Containing Heteroatoms
TABULATED BDES OF C-HALOGEN BONDS
C-F Bonds
C-Cl Bonds
C-Br Bonds
C-I Bonds
TABULATED BDES OF O-X BONDS
O-H Bonds
O-O Bonds
O-C Bonds
O-N Bonds
O-S, O-Halogen, and O-P Bonds
TABULATED BDES OF N-X BONDS
N-H Bonds
N-N Bonds
N-C Bonds
N-S Bonds
N-Halogen Bonds
TABULATED BDES OF S-X BONDS
S-H Bonds
S-S Bonds
S-C Bonds
S-Halogen and S-P Bonds
TABULATED BDES OF Si-, Ge-, Sn-, P-, AND Se-X BONDS
Si-X Bonds
Ge-X Bonds
Sn-X Bonds
P-X Bonds
Se-X Bonds
TABULATED BDES IN SOME INORGANIC COMPOUNDS
HEATS OF FORMATION OF ATOMS, INORGANIC AND ORGANIC RADICALS
Gaseous Atoms
Small Inorganic Radicals in the Gas Phase
Organic Radicals in the Gas Phase
Group Additivity Values for Organic Radicals
REFERENCES
INDEX OF COMPOUND CLASSES
INDEX OF COMPOUND NAMES

O autorze

Luo, Yu-Ran