Fundamental Research in Homogeneous Catalysis: Volume 2

ISBN-13: 9781461570431 / Angielski / Miękka / 2012 / 305 str.

Y. Ishii

Opis

The upsurge in development of homogeneous catalysis in both aca demic and industrial areas has prompted us to organize the Second Interna tional Workshop at Shiga, Japan, 1977. The objective of this workshop was similar to that of the first: to identify opportunities for the solution of energy problems and industrial production problems by homogeneous catalysis. This workshop on homogeneous catalysis was sponsored by the Toray Science Foundation, the Yoshida Foundation for Science and Technology, the Yamada Science Foundation, and the National Science Foundation. The Robert A. Welch Foundation Grant A-420 partially supported the time spent by M. Tsutsui for the organization of the workshop and the edi torial work of these proceedings. Organizing Committee, April, 1978 Jack Halpern (U.S.A.) Yoshio Ishii Oapan) Jiro Tsuji Oapan) Minoru Tsutsui (U.S.A.) Akio Yamamoto Oapan) v Contents Metal Clusters in Catalysis XVII: Catalytic Hydrocarbon Reactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 E.L. Muetterties Cluster Catalysis: Homogeneous Catalytic Oxidation of Carbon Monoxide and of Ketones with Molecular Oxygen Using Complexes of Rhodium(O), Iridium(I), and Platinum(O). . . . . . 11 D.M. Roundhill Metal Carbonyl Catalysis of Carbon Monoxide Reactions. . . . . . . . . . 25 . R.B. King, A.D. King, Jr., M.Z. Iqbal, C.C. Frazer and R.M. Hanes Activation of Saturated Hydrocarbons by Ruthenium(I) Complexes? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 . . . . . . . . . . Brian R. James and Daniel K.W. Wang Oxidative Addition to Metal Atoms: Mechanism, Use of Resultant Reactive RMX and R2M Species in Homogeneous Catalysis Processes and Metal Atom-Alkane Interactions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 . . . . . . . . . .

Spis treści

Metal Clusters in Catalysis XVII: Catalytic Hydrocarbon Reactions.- Cluster Catalysis: Homogeneous Catalytic Oxidation of Carbon Monoxide and of Ketones with Molecular Oxygen Using Complexes of Rhodium(0), Iridium(I), and Platinum(0).- Metal Carbonyl Catalysis of Carbon Monoxide Reactions.- Activation of Saturated Hydrocarbons by Ruthenium(I) Complexes?.- Oxidative Addition to Metal Atoms: Mechanism, Use of Resultant Reactive RMX and R2M Species in Homogeneous Catalysis Processes and Metal Atom—Alkane Interactions.- Organometallic Derivatives of the Transition Elements. III. The Reaction of Alkynes with Transition Metal Atoms.- Hydroalumination of Olefins Catalyzed by Transition Metal Compounds.- Oxidative Addition of Acyl and Alkyl Halides to Rhodium(I) and Iridium (I) Complexes and Alkyl Group Isomerization.- Transition Metal Formyl Complexes and Transition Metal Anions; Synthesis by Trialkylborohydride Attack on Metal Carbonyl Compounds.- Electronic Control of Stereochemistry in Carbon—Carbon Bond Formation at Metal Centers.- ?-? Rearrangements of Organotransition Metal Compounds in Homogeneous Catalysis.- Chiral Ferrocenylphosphines and Their Use as Ligands for Transition Metal Complex Catalyzed Asymmetric Synthesis.- Homogeneous Asymmetric Hydrogenation and Hydrosilylation of Keto Esters Catalyzed by Chiral Rhodium Complexes.- Metallacycles in Organotransition Metal Chemistry.- Nickel(O) Catalyzed Reactions of Bicyclo[ 1.1.0] Butanes with Electron-Deficient Olefins.- Significance of Dioxygen Activation on Model Catalytic Oxygenation with Cobalt-Schiff’s Base Complexes.- On the Mechanism of Vanadium Catalyzed Oxidation by t-Butyl Hydroperoxide.- Synthetic Reactions by Copper Complex Catalysts.- Synthetic Analogues of the Active Site in Blue Copper Proteins.