Fortschritte Der Chemie Organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products

ISBN-13: 9783211834282 / Angielski / Twarda / 2000 / 256 str.

W. Herz; H. Falk; G. W. Kirby

Opis

The volumes of this classic series, now referred to simply as "Zechmeister" after its founder, L. Zechmeister, have appeared under the Springer Imprint ever since the series' inauguration in 1938. The volumes contain contributions on various topics related to the origin, distribution, chemistry, synthesis, biochemistry, function or use of various classes of naturally occurring substances ranging from small molecules to biopolymers. Each contribution is written by a recognized authority in his field and provides a comprehensive and up-to-date review of the topic in question. Addressed to biologists, technologists, and chemists alike, the series can be used by the expert as a source of information and literature citations and by the non-expert as a means of orientation in a rapidly developing discipline.

Spis treści

Naturally Occurring Isocyano/Isothiocyanato and Related Compounds.- 1. Introduction.- 1.1. Occurrence and Distribution.- 1.2. Nomenclature and Structural Representation.- 1.3. Isolation and Identification.- 1.3.1. Physical and Chemical Properties.- 1.3.2. Spectral Characterization.- 2. Monoterpene Indole Alkaloids from Blue-Green Algae.- 2.1. C21-Compounds.- 2.1.1. Hapalindolcs.- 2.1. 1. 1. Tetracyclic Hapalindoles 1.- 2.1.1.2. Tricyclic Hapalindoles 1.- 2.1.2. Fischerindoles.- 2.2. Oxindoles and Modified Oxygenated C’21-Indoles.- 2.2.1. Hapaloxindoles.- 2.2.2. Hapalonamides.- 2.2.3. Hapalindolinones.- 2.2.4. Welwitindolinoncs.- 2.3. C26-Indole Alkaloids.- 2.3.1. Ambiguine Isonitriles.- 2.4. Reactions of Hapalindoles.- 2.5. Syntheses of Hapalindolcs.- 3. Marine Diterpenes from Sponges.- 3.1. Acyclics.- 3.2. Kalihinanes.- 3.2.1. Kalihinols from Actin/he/hi Sponges.- 3.2.2. Tetrahydropyrans.- 3.2.3. Tetrahydrofurans.- 3.2.4. Dihydropyrans.- 3.3. Amphilectanes.- 3.3.1. Isocyanoditcrpencs from Crnihastela hooperi.- 3.3.2. Amphilectanes.- 3.3.3. Cycloamphilectanes.- 3.3.4. Isocycloamphilectanes.- 3.3.5. Veo-and “Prc”-amphilcctadicncs.- 3.4. Diterpene Syntheses.- 4. Marine Sesquiterpenes from Sponges.- 4.1. Skeletal Types.- 4.2. The Triads from Axinella cannabina.- 4.3. Sesquiterpenoid Compounds.- 4.3.1. Axanes.- 4.3.2. Aromadendranes.- 4.3.3. Eudesmanes.- 4.3.4. Cadinanes.- 4.3.5. Epimaalianes.- 4.3.6. Spiroaxanes.- 4.3.7. Bisbolanes.- 4.3.8. Guaiane-Types.- 4.3.9. Pupukeanane-Types.- 4.4. Sesquiterpene Syntheses.- 5. Uncommon Marine Analogs.- 5.1. Carbonimidic Dichloride Terpenes.- 5.2. Isothiocyanato and Thiocyanato Nonterpenoids.- 5.2.1. Ascidians.- 5.2.2. Sponges.- 5.3. Marine Cyanides.- 6. Other Terrestrial Compounds.- 6.1. Isocyanides from Lower Organisms.- 6.1.1. Xanthocillins.- 6.1.2. Cyclopentanes.- 6.1.2.1. Dermadin-Types 12.- 6.1.2.2. Trichoviridin-Types 12.- 6.2. Other Terrestrial Isocyanides.- 6.3. Other Terrestrial Analogs.- 6.4. Syntheses of Terrestrial Isocyanides.- 7. Biogenesis and Biosynthesis.- 7.1. Monoterpene Indole Alkaloids.- 7.2. Diterpenes.- 7.3. Sesquiterpenes.- 7.4. Other Terrestrial Isocyanides and Isothiocyanates.- 8. Discussion and Summary.- Addendum.- Acknowledgment.- References.- Sulfur-Containing Amides from Glycosmis Species (Rutaceae).- I. Introduction.- 2. Isolation and Structure Elucidation.- 2.1. Analytical HPLC and Preparative MPLC.- 2.2. Structure Elucidation and Stereochemistry.- 3. Methylthiopropenoic Acid Amides.- 4. Methylsulfinylpropenoic Acid Amides.- 5. Methylsulfonylpropenoic Acid Amides.- 5.1. p-Prenyloxyphenethylamides.- 5.2. O-Geranyltyramides.- 5.3. p-O-Geranyldopamides.- 5.4. 13-Hydroxy-O-geranyltyramides.- 6. Methylthiocarbonic Acid Amides.- 7. Synthesis of Biogenic Sulfur-Containing Amides.- 8. Biological Activity.- 9. Biosynthesis.- 10. Chemotaxonomy.- Appendix: Sulfur-Containing Bisamides from Aglaia Species (Meliaceae).- References.- Author Index.