Expanded Clays and Other Microporous Solids

ISBN-13: 9781468488685 / Angielski / Miękka / 2013 / 379 str.

M. L. Occelli; H. Robson

Opis

From the symposium on Advances in Zeolites and Pillared Clays Synthesis, sponsored by the Petroleum Chemistry Division of the American Chemical Society experts from around the world review: You'll find everything you've ever wanted to know about zeolites and pillared clays: For the novice - how to information on zeolite synthesis. For the expert - a survey of advances in novel zeolites. The mechanism of zeolite crystallisation and crystal growth; spectroscopic characterization of reactants and reaction intermediates; chemistry of silicate solution and reaction effects on crystallization products; the role of organic additives in zeolite formation; novel synthesis methods and procedures for zeolites and pillared clays preparation; new pillaring agents and pillared products; delaminated clays.

Spis treści

1 Approaches to the Synthesis of Supergallery Pillared Clays.- 2 Ga13, GaAl12, and Al13 Polyoxocations and Pillared Clays.- 3 Optimization of the Pillaring of a Saponite.- 4 Preparation and Properties of Pillared Synthetic Boron-Containing Saponite.- 5 Surface and Cracking Properties of Expanded Clays Dried with a Supercritical Fluid.- 6 TEM Characterization of Pillared Rectorites.- 7 Anionic Clays: Trends in Pillaring Chemistry.- 8 Preparation and Characterization of Borate Pillared Anionic Clay.- 9 Layered Silicates: The Protonation Behavior of KHSi2O5.- 10 Synthesis of Dioctahedral 2:1 Layered Silicates in an Acid and Fluoride Medium.- 11 Direct Synthesis of Novel Intercalated Layer Silicates of the Metal Silicate Type.- 12 Pillaring of Layered Inorganic Compounds: Fundamentals.- 13 Intercalation Properties of Layered Metal (IV) Phosphates Towards Organic Bases, Metal Complexes and Metal Oxides.- 14 Microporous Pillared Mica with Cation-Incorporated Silicate Surfaces.- 15 Oxygen Adsorption Properties of Microporous Silica Derived from Layered Siloxene by Oxidation.- 16 Design and Synthesis of Carbon Molecular Sieves for Separation and Catalysis.- 17 Hydrothermal Synthesis of Manganese Oxides with Tunnel Structures.- 18 Molecular Chemical Aspects of Silica Gel Formation.