Enolization Reactions Mediated by S-Block Metal Amide Reagents » książka
Enolization Reactions Mediated by S-Block Metal Amide Reagents
ISBN-13: 9783838300160 / Angielski / Miękka / 2009 / 220 str.
The enolization of ketonic substrates is a cornerstone reaction in modern organic synthesis. The research in this book is split into three main sections, with the investigation of s-block metal enolate chemistry being the underlying theme: The first section focuses on the synthesis and characterization of a series of homo- and heterobimetallic potassium and calcium enolates. The second section concentrates on an investigation into the utility of Ca(HMDS)2 to mediate the enolization of ketonic substrates. The final section outlines a detailed mechanistic study for the enolization of propiophenone mediated by Mg(HMDS)2 in toluene.
The enolization of ketonic substrates is acornerstone reaction in modern organicsynthesis. The research in this book is split intothree main sections, with the investigation ofs-block metal enolate chemistry being the underlyingtheme: The first section focuses on the synthesis andcharacterization of a series of homo- andheterobimetallic potassium and calcium enolates. Thesecond section concentrates on an investigation intothe utility of Ca(HMDS)2 to mediate the enolizationof ketonic substrates. The final section outlines adetailed mechanistic study for the enolization ofpropiophenone mediated by Mg(HMDS)2 in toluene.
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