Electrochemistry of N4 Macrocyclic Metal Complexes: Volume 2: Biomimesis, Electroanalysis and Electrosynthesis of Mn4 Metal Complexes

ISBN-13: 9783319810140 / Angielski / Miękka / 2018 / 436 str.

Zagal, Jose H.

Opis

This new edition describes the state of the art regarding metal complexes of N4-ligands, such as porphyrins and phthalocyanines. Volume 2 focuses on the electro assisted use of N4 complexes as biomimetic models for studying several biological redox processes. It focuses on molecular oxygen transport and catalytic activation to mimic monooxygenase enzymes of the cytochrome P450 in particular. It also examines N4 complexes' use as catalysts for the oxidative degradation of various types of pollutants (organo-halides, for example) and residual wastes. The remarkable activity of these complexes towards a large number of significantly relevant biological compounds makes them excellent candidates as electrode modifiers for electrochemical sensing. This volume also discusses applications of N4 Macrocyclic Metal Complexes to photoelectrochemistry and photocatalysis, and concludes with an exciting section on Electrosynthesis of N4.

Spis treści

Section 3: Biomimesis

1. Supramolecular Hybrid Organic/Inorganic Nanomaterials Based On Metalloporphyrins and Phtalocyanines
2. Electrochemically Activated Catalytic Pathways of Human Metabolic Cytochrome P450s in Ultrathin Films

Section 4: Electroanalysis and Electrochemical Sensors

1. Applications of MN4 Macrocyclic Metal Complexes in Electroanalysis
2. Spectroelectrochemistry of Phthaloctyanines
3. Electroanalysis of Hydrazine and Related Compounds By Oxidation Promoted with MN4 Macrocyclics
4. Modification of Electrode Surfaces with Metallophthalocyanine Nanomaterial Hybrids
5. Modified Electrodes with MN4 Complexes: TConception and Electroanalytical Performances for the Detection of Thiols
6. Electrochemical Oxidation and Electroanalysis of Organic Pollutants on Electrodes Modified with Metallophthalocyanines (MPcs)
7. Spirobifluorenyl-Porphyrins for Homogenous or Heterogeneous Catalysis
8. Electrosynthesis of Oligo- and Polyporphyrins Based on Oxidative Coupling of Macrocycles