Early Transition Metal Clusters with Pi-Donor Ligands

ISBN-13: 9780471186069 / Angielski / Twarda / 1996 / 304 str.

Malcolm H. Chisholm; M. H. Chisholm

Opis

The discovery and evolution of oranometallic cluster chemistry is a major event in the development of inorganic chemistry. This is the second volume in the series 'The Chemistry of Metal Clusters' edited by Du Shriver, Herb Kaesz, and Richard Adams.

This volume focuses on the chemistry of the early transition elements in their lower and middle oxidation states, i.e., halide, sulfide, oxide, phosphate, alkoxide, and related o-donor ligands. The key feature linking all these complexes in metal-metal bonding is the presence of pi-donor ligands.

Spis treści

From the Contents:
Introduction and Scope/
Zeolite Physical and Chemical Characteristics and Their Impact on Diffusion/Application of Diffusional Transport Phenomena to Catalysis/
Diffusion in Zeolites –
Theoretical Considerations/
Measurement of Molecular Transport in Zeolites/Principles of Shape Selectivity/
Examples of the Interplay of Diffusion and Reaction in Shape Selective Reactions/
Impact of Shape Selective Zeolites in Industrial Applications/
Conclusions

Blurb

Early Transition Metal Clusters with –Donor Ligands Edited by Malcolm H. Chisholm The discovery and evolution of organometallic cluster chemistry is a major event in the development of inorganic chemistry. Early Transition Metal Clusters with –Donor Ligands, the second volume in the Chemistry of Metal Cluster Complexes Series (D.F. Shriver, H.D. Kaesz, R.D. Adams, Editors), focuses on the chemistry of the early transition elements in their lower and middle oxidation states, such as halide, sulfide, oxide, phosphate, alkoxide, and related hard donor ligands. The presence of –donor ligands links all of these complexes in metal–metal bonding. Written by highly respected authorities in the field of organometallic cluster chemistry, this book will be of interest to inorganic chemists, organometallic chemists, solid state chemists, materials scientists, and graduate students in inorganic chemistry. Also available from VCH: The Chemistry of Metal Cluster Complexes Duward F. Shriver, Herbert D. Kaesz, and Richard D. Adams, Eds. (ISBN 1–56081–012–2)