Donor-Acceptor Cyclopropapyranone

ISBN-13: 9786139861026 / Angielski / Miękka / 2018 / 136 str.

Sumit Mane; Santosh J. Gharpure; Laxminarayan Nanda

Opis

My primary research interests center on the Organic Synthesis and study of Donor-Acceptor cyclopropane chemistry. Research activities include the impact of D-A cyclopropanes and cyclobutanes in organic synthesis and its application towards natural product synthesis. An intramolecular, stereoselective cyclopropanation of vinylogous carbonates with carbenes using copper catalyst is developed for the synthesis of donor-acceptor substituted cyclopropapyranones. Completely regioselective ring cleavage of each of the cyclopropane bonds was achieved under suitable reaction conditions, leading to a diverse array of cyclic ethers. The developed method is utilized in the total synthesis of ( )-diospongin B.

O autorze

Mane, Sumit
Sumit Popat ManeAssistant Professor in Chemistry,BCE Bhagalpur, NH-80, Sabour, Bhagalpur, Bihar-India-813210Motivated and talented, inspires students for their academic and personal excellence. Consistently strives to create a challenging and engaging learning environment in which students become life long scholars and learners.