Chemistry of Organo-Hybrids: Synthesis and Characterization of Functional Nano-Objects

ISBN-13: 9781118379028 / Angielski / Twarda / 2015 / 552 str.

Emmanuel Lacote; Bernadette Charleux; Christophe Coperet

Opis

This book provides readers with a one-stop entry into the chemistry of varied hybrids and applications, from a molecular synthetic standpoint - Describes introduction and effect of organic structures on specific support components (carbon-based materials, proteins, metals, and polymers).
- Chapters cover hot topics including nanodiamonds, nanocrystals, metal-organic frameworks, peptide bioconjugates, and chemoselective protein modification
- Describes analytical techniques, with pros and cons, to validate synthetic strategies
- Edited by internationally-recognized chemists from different backgrounds (synthetic polymer chemistry, inorganic surfaces and particles, and synthetic organic chemistry) to pull together diverse perspectives and approaches

Spis treści

Preface vii

Contributors ix

1 COVALENT ORGANIC FUNCTIONALIZATION AND CHARACTERIZATION OF CARBON NANOTUBES 1
Cécilia Ménard–Moyon

2 FUNCTIONALIZED GRAPHENES 36
Iban Azcarate, David Lachkar, Emmanuel Lacôte, Jennifer Lesage de la Haye, and Anne–Laure Vallet

3 NANODIAMONDS: EMERGENCE OF FUNCTIONALIZED DIAMONDOIDS AND THEIR UNIQUE APPLICATIONS 69
Maria A. Gunawan, Paul Kahl, Didier Poinsot, Bruno Domenichini, Peter R. Schreiner, Andrey A. Fokin, and Jean–Cyrille Hierso

4 TITANIA–BASED HYBRID MATERIALS: FROM MOLECULAR PRECURSORS TO THE CONTROLLED DESIGN OF HIERARCHICAL HYBRID MATERIALS 114
Laurence Rozes, Loïc D Arras, Chloé Hoffman, François Potier, Niki Halttunen, and Lionel Nicole

5 FUNCTIONALIZATION OF ZIRCONIUM OXIDE SURFACES 168
Marc Petit and Julien Monot

6 FUNCTIONAL METAL ORGANIC FRAMEWORKS: SYNTHESIS AND REACTIVITY 200
Flavien L. Morel, Xiaoying Xu, Marco Ranocchiari, and Jeroen A. van Bokhoven

7 SURFACE CHEMISTRY OF COLLOIDAL SEMICONDUCTOR NANOCRYSTALS: ORGANIC, INORGANIC, AND HYBRID 233
Richard Brutchey, Zeger Hens, and Maksym V. Kovalenko

8 COVALENT ORGANIC FUNCTIONALIZATION OF NUCLEIC ACIDS 272
Michel Arthur and Mélanie Etheve–Quelquejeu

9 CHEMOSELECTIVE PROTEIN MODIFICATIONS: METHODS AND APPLICATIONS FOR THE FUNCTIONALIZATION OF VIRAL CAPSIDS 299
Divya Agrawal and Christian P. R. Hackenberger

10 CYCLODEXTRINS METAL HYBRIDS 349
Maxime Guitet, Mickaël Ménand, and Matthieu Sollogoub

11 POST–FUNCTIONALIZATION OF POLYMERS VIA ORTHOGONAL LIGATION CHEMISTRY 395
Anja S. Goldmann, M. Glassner, Andrew J. Inglis, and Christopher Barner–Kowollik

12 POLYMER PROTEIN/PEPTIDE BIOCONJUGATES 466
Paul Wilson, Julien Nicolas, and David M. Haddleton

13 HYBRID MATERIALS BUILT FROM (PHOSPHORUS) DENDRIMERS 503
Anne–Marie Caminade, Beatrice Delavaux–Nicot, and Jean–Pierre Majoral

Index

O autorze

Bernadette Charleux is a Professor at the Claude Bernard Lyon 1 University, and a Senior Member of the Institut Universitaire de France.

Christophe Copéret (CCH) is a Professor in the Department of Chemistry (Institute of Inorganic chemistry) at ETH Zürich.

Emmanuel Lacôte is CNRS Research Director at CPE Lyon.

Blurb

A One–Stop Entry into Hybrid Chemistry and Applications

Hybrid materials are made by linking molecules to supports in order to create optimal combinations and enhanced functionality. Successful synthesis requires a deep understanding of molecular–level events and the ability to control them through design. This book acts a step–by–step guide for designing organo–hybrid materials. Focusing on a molecular synthetic approach, chapters provide:

 Up–to–date strategies and methods of controlling functions of attachments
 Information about common classes of supports, including polymers and biopolymers, carbons, oxides, and nanostructures
 Details of specific supports, their synthesis, installation of organic substituents, effects on properties.
 Analytical techniques, with pros and cons, to validate synthetic strategies
 Hot topics: nanodiamonds, metal–organic frameworks, and chemoselective postsynthetic protein modification.

Combining the perspectives of internationally–recognized chemists from synthetic, polymer, organic, and inorganic research backgrounds, this book pulls together diverse approaches to provide a well–rounded, interdisciplinary knowledge base about organo–hybrid materials.