Chemical Principles of Nanoengineering

ISBN-13: 9783527339556 / Angielski

San Diego) Tao Andrea R. (University of California

Opis

This textbook serves as an introduction to the fundamental chemistry principles that guide the synthesis and dictate the properties of nanomaterials. Key chemistry and engineering concepts are looked at through the lens of important and well-characterized nanomaterials, including quantum dots, carbon nanotubes, graphene, and noble metal nanocrystals. The book provides a focused, detailed look into the chemical bonding and structure of the most important, selected nanomaterials. Special emphasis is placed on how a nanomaterial's properties are derived from chemical bonding at the atomic and molecular level. Thereby the textbook provides the reader with a clear understanding of how the chemical and physical properties of a material change within a continuum of length scales: from atoms and molecules to nanostructures, surfaces, and finally, bulk solids.

Spis treści

1. ATOMS AND MOLECULES: THE BUILDING BLOCKS OF NANOMATERIALSThe Hydrogen AtomMolecular StructureValence Bond TheoryMolecular Orbital Theory2. EXTENDED SOLIDS: BONDING IN 0-D TO 3-D MATERIALSTight-Binding ModelBand StructureDensity of States3. CARBON NANOMATERIALSHybridized BondingGraphene to DiamondoidsA Closer Look: Carbon Nanotubes4. DESCRIPTIVE CRYSTAL CHEMISTRYPacking StructuresThe Unit Cell and Bravais LatticesMiller NotationDiffraction5. THE IMPORTANCE OF SURFACESSurface Energy and PressureSolid SurfacesMetal Nanoparticles and Clusters6. CHEMICAL INTERACTIONSElectrostatic ForcesVan der Waal ForcesHydrophobic ForcesSelf-Assembly

O autorze

Andrea Tao is Assistant Professor in NanoEngineering at the University of California, San Diego in La Jolla, USA. She earned her BSc in Chemistry & Physics from Harvard University in 2002 and a PhD in Chemistry from the University of California, Berkeley in 2007. Professor Tao has been active in nanomaterials research for the past fifteen years and has authored numerous scientific publications in the nanoparticle synthesis and self-assembly.