Chemical Kinetics

ISBN-13: 9789067644303 / Angielski / Twarda / 2005 / 528 str.

E. B. Burlakova;A.E. Shilov;Sergei D. Varfolomeev

Opis

The volume is devoted to the problem of chemical kinetics on modern level. The book is including information about chemical physics of nanocomposites, degradation, stabilization and flammability of polymeric materials as well as free radical mechanism of oxidation of organic compounds, thermostability, mechanism of action of catalytical systems and inhibitors in free radical reactions in liquid and solid phase, pure and applied chemistry of antioxidants (synthesis and application), ionic reactions, effect of chemoluminescence in the processies of oxidation, biodegradation and application of polymers in medicine, problems of adhesion of microorganizmus on the surface of materials, thermo-, photo- and hydrolitic reactions, creation of new ecologically friendly flame retardants for polymers, polymer composites and polymer blends as well as filled polymers.

Spis treści

PREFACE, CHAPTER l. Brief information about Professor N. M. Emanuel, CHAPTER 2. Polymer nanocomposites of lowered combustibility on the base of lamellar silicates, CHAPTER 3. Nano-phases and kinetic model of chain reactions of polypropylene with dibenzoyl peroxide, CHAPTER 4. Structural-dynamic particularities of interphase layers in filled polymers, CHAPTER 5. Substantial and formal approaches to analysis of kinetic data, CHAPTER 6. Free-radical mechanisms of formation of polysaccharides radiation destruction products, CHAPTER 7. Mechanism of generation of stable nitrogen-containing radicals in the presence of nitrogen oxides, CHAPTER 8. Heat stability ofvinylchloride polymers subjected intensive force influences of the pressure with shear type, CHAPTER 9. Macroscopic stages and kinetic classification of physical-chemical processes, CHAPTER 10. Supramolecular catalysis of a-oxycyclohexyl peroxides decomposition by tetraethylammonium bromide, CHAPTER 11. Kinetics and mechanism of ozonized oxidation of ketones, CHAPTER 12. Theoretical and applied aspects of chemistry of spatio-hindered phenols, CHAPTER 13. Solution of the problem of selective oxidation of alkylarens by molecular oxygen into corresponding hydroperoxides. Catalysis initiated by Ni(II), Co(ll) and Fe(lll) complexes activated by additives of electron-donor mono- or multidentate extra-kigands, CHAPTER 14. Liquid-phase oxidation of alkanes in the presence of metals compounds, CHAPTER 15. Photo-induced bonding of water and alcohols to 1,2-dihydroquinolines. Mechanism of reaction and particularities of interaction of formed carbocations with ion and molecular nucleophils, CHAPTER 16. Reactions of ozone with aromatic compounds, CHAPTER 17. Chemiluminescence in N.M. Emanuel's laboratory and in N.M. Emanuel Institute, CHAPTER 18. Mathematical models of tumor processes and strategies of chemotherapy, CHAPTER 19. Kinetic model of 13-carotene. Influence of oxygen partial pressure, CHAPTER 20. Synergism and antagonism in processes of polymers phototransformation and light stabilization, CHAPTER 21. Bio-damages of materials. Adhesion of microorganisms on materials surface, CHAPTER 22. One-stage method of catalytic oxidation of vegetal raw materials by oxygen. Novel ecologically pure products and perspectives of their practical use, CHAPTER 23. EPR-spectroscopy of complex polymer systems, CHAPTER 24. Modification of polycyanurates by polyethers, polyesters and polyurethanes. Hybrid and interpenetrating polymer networks, CHAPTER 25. On the nanometric particle-like local structures and their implications in polymer behaviour, CHAPTER 26. Fractal physical chemistry of polymer solutions, CHAPTER 27. The structural treatment of Ouctuation free volume in amorphous state of polymers, CHAPTER 28. Transport of water as structurally sensitive process characterizing morphology of biodegradable polymer systems

O autorze

Elena Burlakova, Alexander Evgen'evich Shilov, Sergey Dmitrievich Varfolomeev, Gennady Zaikov